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A70909

(+)-6-氨基青霉烷酸

Name: (+)-6-氨基青霉烷酸
Brand: ALDRICH

96%

别名:

(2S,5R,6R)-6-氨基-3,3-二甲基-7-氧代-4-硫杂-1-氮杂双环[3.2.0]庚烷-2-羧酸, 6-APA

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关于此项目

经验公式（希尔记法）:

C₈H₁₂N₂O₃S

化学文摘社编号:

551-16-6

分子量:

216.26

UNSPSC Code:

12352005

NACRES:

NA.22

PubChem Substance ID:

24891174

EC Number:

208-993-4

Beilstein/REAXYS Number:

15080

MDL number:

MFCD00005176

Assay:

96%

Form:

powder

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属性

Quality Level

200

assay

96%

form

powder

optical activity

[α]22/D +276.3°, c = 1.2 in 0.1 M HCl

mp

198-200 °C (dec.) (lit.)

antibiotic activity spectrum

Gram-positive bacteria

mode of action

cell wall synthesis | interferes

storage temp.

2-8°C

SMILES string

CC1(C)S[C@@H]2[C@H](N)C(=O)N2[C@H]1C(O)=O

InChI

1S/C8H12N2O3S/c1-8(2)4(7(12)13)10-5(11)3(9)6(10)14-8/h3-4,6H,9H2,1-2H3,(H,12,13)/t3-,4+,6-/m1/s1

InChI key

NGHVIOIJCVXTGV-ALEPSDHESA-N

说明

General description

(+)-6-氨基青霉烷酸是不同青霉素的核心部分。可由苄青霉素硅烷基酯通过酰胺键断裂制备。(+)-6-氨基青霉烷酸包被在银纳米颗粒 (6APA-AgNPs) 上，使其具有检测人红细胞中铬 (IV) 的能力。

化学结构式：β-内酰胺

Application

（+）-6-氨基青霉烷酸可作为原料，用于通过界面缩聚反应与有机锡二卤化物反应合成（6S，7S）-头孢菌素和有机锡多胺酯。

它与较高氨基酸席夫碱反应形成相应的β-内酰胺衍生物4

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pictograms

GHS07

signalword

Warning

hcodes

H319

pcodes

P264 - P280 - P305 + P351 + P338 - P337 + P313

Hazard Classifications

Eye Irrit. 2

存储类别

11 - Combustible Solids

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Chromium scavenging ability of silver nanoparticles in human erythrocytes, real samples and their effect on the catalase enzyme.

Rasheed W, et al.

New. J. Chem., 40(4), 3793-3802 (2016)

An efficient nonenzymatic conversion of benzylpenicillin to 6-aminopenicillanic acid.

Weissenburger HWO and Van Der Hoeven MG.

Rec. Trav. Chim., 89(10), 1081-1084 (1970)

A process to produce penicillin G acylase by surface-adhesion fermentation using Mucor griseocyanus to obtain 6-aminopenicillanic acid by penicillin G hydrolysis.

José Luis Martínez-Hernández et al.

Applied biochemistry and biotechnology, 160(7), 2045-2053 (2009-09-22)

The production of extracellular and mycelia-associated penicillin G acylase (maPGA) with Mucor griseocyanus H/55.1.1 by surface-adhesion fermentation using Opuntia imbricata, a cactus, as a natural immobilization support was studied. Enzyme activity to form 6-aminopencillanic acid (6-APA) from penicillin G was

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全球贸易项目编号

货号	GTIN
A70909-10G	04061833383506
A70909-50G	04061833383513