A88255
p-茴香胺
99%
别名:
4-氨基苯甲醚, 4-甲氧基苯胺
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关于此项目
线性分子式:
CH3OC6H4NH2
化学文摘社编号:
分子量:
123.15
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
471556
Assay:
99%
Form:
solid
Quality Level
assay
99%
form
solid
autoignition temp.
959 °F
bp
240-243 °C (lit.)
mp
56-59 °C (lit.)
SMILES string
COc1ccc(N)cc1
InChI
1S/C7H9NO/c1-9-7-4-2-6(8)3-5-7/h2-5H,8H2,1H3
InChI key
BHAAPTBBJKJZER-UHFFFAOYSA-N
Application
在存在金催化剂的条件下，对茴香胺可进行有氧氧化，形成芳族偶氮化合物。
对茴香胺可用于：
对茴香胺可用于：
- 在手性Bronsted酸催化下非对映选择性和对映选择性合成CF3-取代的偶氮啶。
- 在Yb(OTf)3催化下，通过与乙醛酸乙酯和乙炔基（苯基）硒烷的多组分Povarov反应，制备4-有机硒基喹啉。
- 作为分两步合成3-氟-6-甲氧基喹啉的原料。,
- 以三氟甲磺酸银(I)为催化剂，通过与末端炔烃和二乙基甲酰基膦酸酯水合物反应制备N-PMP保护的α-氨基炔丙基膦酸酯。
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signalword
Danger
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
flash_point_f
251.6 °F - closed cup
flash_point_c
122 °C - closed cup
Hazard Classifications
Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 3 - Carc. 1B - STOT RE 2
法规信息
危险化学品
非剧毒-急性毒性1
此项目有
Dima A Sabbah et al.
Medicinal chemistry (Shariqah (United Arab Emirates)), 14(7), 695-708 (2018-04-14)
Phosphoinositide 3-kinase α (PI3Kα) is an attractive target for anticancer drug design. Target compounds were designed to probe the significance of alcohol and imine moieties tailored on a benzoin scaffold to better understand the structure activity relation (SAR) and improve
A Facile Two-Step Synthesis of 3-Fluoro-6-methoxyquinoline
Li B, et al.
Organic Process Research & Development, 12(6), 1273-1275 (2008)
Silver (I) triflate-catalyzed direct synthesis of N-PMP protected α-aminopropargylphosphonates from terminal alkynes
Dodda R and Zhao C
Organic Letters, 9(1), 165-167 (2007)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| A88255-1KG | 04061833400807 |
| A88255-100G | 04061835370085 |
| A88255-250G | 04061835370092 |
| A88255-5G | 04061835370108 |