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Merck
CN

B17905

苄基溴

reagent grade, 98%

别名:

α-溴甲苯

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关于此项目

线性分子式:
C6H5CH2Br
化学文摘社编号:
分子量:
171.03
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
202-847-3
Beilstein/REAXYS Number:
385801
MDL number:
Assay:
98%
Form:
liquid
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grade

reagent grade

Quality Level

vapor density

5.8 (vs air)

assay

98%

form

liquid

impurities

≤0.5% p-bromotoluene

refractive index

n20/D 1.575 (lit.)

bp

198-199 °C (lit.)

mp

−3-−1 °C (lit.)

density

1.438 g/mL at 25 °C (lit.)

SMILES string

BrCc1ccccc1

InChI

1S/C7H7Br/c8-6-7-4-2-1-3-5-7/h1-5H,6H2

InChI key

AGEZXYOZHKGVCM-UHFFFAOYSA-N

General description

苄基溴是一种芳香卤化物,主要用作保护剂,通过 O-苄基化反应保护醇的羟基。

Application

苄基溴已被用作通过原子转移自由基聚合反应合成聚(苯乙烯-b-甲基丙烯酸甲酯)共聚物的引发剂。它可以与1,2-二甲基咪唑发生Menschutkin反应,形成3-苄基-1,2-二甲基咪唑鎓溴化物。


pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 2

flash_point_f

186.8 °F - closed cup

flash_point_c

86 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

危险化学品

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历史批次信息供参考:

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A novel acid-catalyzed O-benzylating reagent with the smallest unit of imidate structure.
Yamada K
Organic Letters, 14(19), 5026-5029 (2012)
Yukiko Fujii et al.
Environmental pollution (Barking, Essex : 1987), 247, 312-318 (2019-01-28)
We investigated the profiles and levels of perfluoroalkyl carboxylic acid (PFCA) contamination in Pacific cod (Gadus macrocephalus) from the North Pacific Ocean. The mean concentrations of PFCAs containing 8 to 14 carbon atoms (C8-C14) in edible Pacific cod muscle ranged
Vanderlisa Rita Meleti et al.
Acta tropica, 202, 105248-105248 (2019-11-05)
This paper reports the synthesis of (±)-licarin A 1, a dihydrobenzofuran neolignan, resultant of an oxidative coupling reaction of isoeugenol and horseradish peroxidase (HRP) enzyme. Following, three semi-synthetic derivatives from this compound were obtained: benzylated (±)-licarin A 2, methylated (±)-licarin



全球贸易项目编号

货号GTIN
B17905-100G04061833426401
B17905-25G04061833426425
B17905-2.5KG04061833426418
B17905-500G04061833426432