vapor pressure
0.03 mmHg ( 40 °C)
Quality Level
assay
98%
reaction suitability
core: iron, reagent type: catalyst
bp
249 °C (lit.)
mp
172-174 °C (lit.)
λmax
358 nm
storage temp.
2-8°C
SMILES string
[Fe].[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2
InChI
1S/2C5H5.Fe/c2*1-2-4-5-3-1;/h2*1-5H;
InChI key
DFRHTHSZMBROSH-UHFFFAOYSA-N
Application
二茂铁（二环戊二烯基铁）可用于：
- 用作不对称催化中的手性配体支架。
- 染料敏化太阳能电池应用中的二茂铁基电解质。
- 合成不对称二茂铁配体，可用作交叉偶联、氢化、烯丙基取代的催化剂。
- 通过化学气相沉积法合成二维六方有序介孔碳（CMK-5），用作甲醇氧化的催化剂载体。
- 合成二茂铁与富勒烯的分子杂化物（巴基二茂铁）。
- 制备二茂铁盐，用作温和氧化剂。
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signalword
Danger
Hazard Classifications
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 1 - Flam. Sol. 1 - Repr. 1B - STOT RE 2 Inhalation
target_organs
Liver
存储类别
4.1B - Flammable solid hazardous materials
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
商品
近十年来出现了原子层沉积（ALD）技术以满足各种需求，包括半导体器件小型化、多孔结构上的保形沉积和纳米颗粒涂层。ALD基于两个相继的自限性表面反应。
Atomic layer deposition meets various needs including semiconductor device miniaturization and nanoparticle coating.
The syntheses and catalytic applications of unsymmetrical ferrocene ligands
Atkinson RCJ, et al.
Chemical Society Reviews, 33(33), 313-328 (2004)
Muneebah Adams et al.
Dalton transactions (Cambridge, England : 2003), 42(13), 4677-4685 (2013-01-31)
A series of aryl-functionalized and ferrocenyl monothiosemicarbazone compounds (L1-L4) were synthesized in moderate yields via a general Schiff-base condensation reaction. The thiosemicarbazone (TSC) ligands were reacted with the ruthenium dimer [Ru(Ar)(μ-Cl)Cl](2) (Ar = benzene; p-cymene) to yield a series of
Sumit Kumar et al.
ACS omega, 3(9), 12106-12113 (2018-10-16)
1H-1,2,3-Triazole tethered imidazole-isatin and imidazole-isatin-thiosemicarbazone conjugates were synthesized and evaluated against MCF-7 and MDA-MB-231 cell lines. Antiproliferative activities of the synthesized conjugates revealed an optimum combination of longer alkyl chain length as spacer and a halogen-substituent on the isatin ring
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| F408-500G | 04061833617489 |
| F408-5G | 04061833617496 |
| F408-100G | 04061833617472 |