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T15601

四氢噻吩

Name: 四氢噻吩
Brand: ALDRICH

99%

别名:

四氢硫杂茂, THT, 噻吩烷, 四甲撑硫

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关于此项目

经验公式（希尔记法）:

C₄H₈S

化学文摘社编号:

110-01-0

分子量:

88.17

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24899981

EC Number:

203-728-9

Beilstein/REAXYS Number:

102392

MDL number:

MFCD00005476

Assay:

99%

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属性

vapor pressure

18 mmHg ( 25 °C)

Quality Level

100

assay

99%

refractive index

n20/D 1.504 (lit.)

bp

119 °C (lit.)

mp

−96 °C (lit.)

density

1 g/mL at 25 °C (lit.)

SMILES string

C1CCSC1

InChI

1S/C4H8S/c1-2-4-5-3-1/h1-4H2

InChI key

RAOIDOHSFRTOEL-UHFFFAOYSA-N

说明

Application

四氢噻吩可用作合成各种环氧化物及其衍生物的试剂。它可用作合成苯并[n.1.0]双环烷烃的催化剂。

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pictograms

GHS02,GHS07

signalword

Danger

hcodes

H225,H302 + H312 + H332,H315,H319,H412

pcodes

P210 - P273 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P312

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2

存储类别

3 - Flammable liquids

wgk

WGK 2

flash_point_f

55.4 °F - closed cup

flash_point_c

13 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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A new protocol for the in situ generation of aromatic, heteroaromatic, and unsaturated diazo compounds and its application in catalytic and asymmetric epoxidation of carbonyl compounds. Extensive studies to map out scope and limitations, and rationalization of diastereo-and enantioselectivities.

Aggarwal VK, et al.

Journal of the American Chemical Society, 125(36), 10926-10940 (2003)

Tetrahydrothiophene-catalyzed synthesis of benzo [n.1.0] bicycloalkanes.

Ye LW, et al.

The Journal of Organic Chemistry, 72(4), 1335-1340 (2007)

Catalytic asymmetric synthesis of epoxides from aldehydes using sulfur ylides with in situ generation of diazocompounds.