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Merck
CN

11291

1-乙基-3-甲基咪唑啉双(三氟甲基磺酰基)亚胺

≥97.0% (NMR)

别名:

EMIM BTI, EMIM TFSI, EMIMIm

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关于此项目

经验公式(希尔记法):
C8H11F6N3O4S2
化学文摘社编号:
分子量:
391.31
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
≥97.0% (NMR)
Form:
liquid
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Quality Level

assay

≥97.0% (NMR)

form

liquid

impurities

<0.5% water

functional group

fluoro

SMILES string

CCn1cc[n+](C)c1.FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F

InChI

1S/C6H11N2.C2F6NO4S2/c1-3-8-5-4-7(2)6-8;3-1(4,5)14(10,11)9-15(12,13)2(6,7)8/h4-6H,3H2,1-2H3;/q+1;-1

InChI key

LRESCJAINPKJTO-UHFFFAOYSA-N

General description

1-乙基-3-甲基咪唑双(三氟甲基磺酰基)酰亚胺[EMIM] [N(Tf)2]是一种室温离子液体(RTIL)。([EMIM] [N(TF)2])作为非水溶剂,由于其具有低蒸气压、高热稳定性、良好的导电性和宽的电化学窗口,因此在电活性物质的电化学研究中优于传统的非质子极性有机溶剂。[EMIM] [N(TF)2]在CO2中显示出良好的溶解性。

Application

[EMIM] [N(TF)2]在微波条件下,可以用作合成氧化锌(ZnO)纳米颗粒的绿色溶剂。它适用于需要具有高CO2溶解度的溶剂的反应。

Physical form

疏水性氟化离子液体

Other Notes

在离子液体中进行对映选择性反应

Legal Information

产品受美国专利 5,827,602 保护,转让给 Covalent Associates, Inc. Woburn, Ma, USA


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Danger

hcodes

Hazard Classifications

Acute Tox. 3 Oral

存储类别

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter



历史批次信息供参考:

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商品

Ionic Liquids serve as non-aqueous electrolytes in electrochemical applications, valued for their conductivity and stability.


Voltammetry of oxygen in the room-temperature ionic liquids 1-ethyl-3-methylimidazolium bis ((trifluoromethyl) sulfonyl) imide and hexyltriethylammonium bis ((trifluoromethyl) sulfonyl) imide: one-electron reduction to form superoxide. Steady-state and transient behavior in the same cyclic voltammogram resulting from widely different diffusion coefficients of oxygen and superoxide
Buzzeo, Marisa C., et al.
The Journal of Physical Chemistry A, 107.42, 8872-8878 (2003)
Thermodynamic properties of mixtures containing ionic liquids. 3. Liquid? liquid equilibria of binary mixtures of 1-ethyl-3-methylimidazolium bis (trifluoromethylsulfonyl) imide with propan-1-ol, butan-1-ol, and pentan-1-ol
Heintz, Andreas, Jochen K. Lehmann, and Christiane Wertz
Journal of Chemical and Engineering Data, 48.3, 472-474 (2003)
Determination of ammonia based on the electro-oxidation of hydroquinone in dimethylformamide or in the room temperature ionic liquid, 1-ethyl-3-methylimidazolium bis (trifluoromethylsulfonyl) imide.
Giovanelli D, et al.
Talanta, 62(5), 904-911 (2004)



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