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Merck
CN

15222

BSTFA

derivatization grade (GC derivatization), LiChropur, ≥99.0%

别名:

BSTFA

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关于此项目

线性分子式:
CF3C[=NSi(CH3)3]OSi(CH3)3
化学文摘社编号:
分子量:
257.40
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
41116105
EC Number:
247-103-9
MDL number:
Beilstein/REAXYS Number:
2050024
Assay:
≥99.0% (GC), ≥99.0%
Form:
liquid
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产品名称

N,O-双(三甲基硅基)三氟乙酰胺, derivatization grade (GC derivatization), LiChropur, ≥99.0%

grade

derivatization grade (GC derivatization)

Quality Level

assay

≥99.0% (GC), ≥99.0%

form

liquid

quality

LiChropur

reaction suitability

reagent type: derivatization reagent
reaction type: Silylations

technique(s)

gas chromatography (GC): suitable

refractive index

n20/D 1.384

bp

45-50 °C/14 mmHg (lit.)

density

0.969 g/mL at 25 °C (lit.)

SMILES string

C[Si](C)(C)O\C(=N\[Si](C)(C)C)C(F)(F)F

InChI

1S/C8H18F3NOSi2/c1-14(2,3)12-7(8(9,10)11)13-15(4,5)6/h1-6H3/b12-7+

InChI key

XCOBLONWWXQEBS-KPKJPENVSA-N

General description

N,O-双(三甲基硅烷基)三氟乙酰胺(BSTFA)是一种优良的硅基化试剂。对于一些空间位阻的一级或二级硝基化合物,N,O-双(三甲基硅基)乙酰胺和BSTFA比常规硅基化条件结果更佳。BSTFA已在胺衍生化中得到应用。其适于羧酸、酚类、脲类、酰胺类、醇类的水化反应。

Application

更多信息请参见产品信息
BSTFA + 1% TMCS(三甲基硅基)溶于乙酸乙酯、乙腈和二氯甲烷溶剂中的情况下,可用于通过气相色谱-质谱联用技术(GC-MS)进行的甾体激素17a-乙炔雌醇(EE2)硅基化反应。此外,其还可用于内源性2-单甘油酯(存在于与大麻素受体结合的犬肠道中)的硅基化。

Legal Information

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany


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Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2

pictograms

FlameExclamation mark

signalword

Warning

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

93.2 °F

flash_point_c

34 °C

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

危险化学品

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分析证书(COA)

Lot/Batch Number

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商品

Results of a study involving the ability few Fluka silylating reagents to form GC-MS-compatible trimethylsilylmethyl derivatives of NSAIDs

相关内容


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Science (2014)
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Schirmer RE.
Science, 2, 215-216 (1990)
R Mechoulam et al.
Biochemical pharmacology, 50(1), 83-90 (1995-06-29)
In this study, we report the isolation from canine intestines of 2-arachidonyl glycerol (2-Ara-Gl). Its structure was determined by mass spectrometry and by direct comparison with a synthetic sample. 2-Ara-Gl bound to membranes from cells transiently transfected with expression plasmids



全球贸易项目编号

货号GTIN
15222-25ML-F04061837683435
15222-10X1ML-F04061838740267
15222-1ML-F04061838740274
15222-5ML-F04061837683442