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Merck
CN

33510

1,10-菲咯啉 一水合物

redox indicator, ACS reagent, puriss. p.a., ≥99.5% (calc. to the dried substance)

别名:

邻菲咯啉 一水合物

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关于此项目

经验公式(希尔记法):
C12H8N2 · H2O
化学文摘社编号:
分子量:
198.22
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
200-629-2
MDL number:
Beilstein/REAXYS Number:
4008096
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产品名称

1,10-菲咯啉 一水合物, ACS reagent, puriss. p.a., ≥99.5% (calc. to the dried substance), for redox titration

Quality Level

grade

ACS reagent, puriss. p.a.

assay

≥99.5% (calc. to the dried substance), 8.5-9.5% water basis

technique(s)

titration: suitable

impurities

8.5-9.5% water

ign. residue

≤0.05% (as SO4)

mp

100-104 °C (lit.), 97-102 °C

suitability

passes test for iron detection, passes test for redox indicator

SMILES string

O.c1cnc2c(c1)ccc3cccnc23

InChI

1S/C12H8N2.H2O/c1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1;/h1-8H;1H2

InChI key

PPQJCISYYXZCAE-UHFFFAOYSA-N

General description

1,10-菲咯啉一水合物是 o -菲咯啉的水合形式。

Application

1,10-菲咯啉一水合物(苯酚的)可用于矿物样品中 Fe 3 + 和总铁的光化学定量。可用作制备 5-硝基-1,10-菲咯啉的起始试剂。
当与铜络合时,具有核酸酶活性,用于研究 DNA-蛋白质相互作用。

Biochem/physiol Actions

金属蛋白酶抑制剂;可与铁、锌和其他二价金属形成螯合物。有效浓度 1-10mM。


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pictograms

Skull and crossbonesEnvironment

signalword

Danger

hcodes

Hazard Classifications

Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1

存储类别

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges



历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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The quantitative assay of minerals for Fe2+ and Fe3+ using 1, 10-phenanthroline: II. A photochemical method.
Stucki JW.
Soil Science Society of America Journal. Soil Science Society of America, 45(3), 638-641 (1981)
Unmesh Jadhav et al.
Molecular cell, 78(1), 141-151 (2020-02-07)
Polycomb repressive complex 2 (PRC2) places H3K27me3 at developmental genes and is causally implicated in keeping bivalent genes silent. It is unclear if that silence requires minimum H3K27me3 levels and how the mark transmits faithfully across mammalian somatic cell generations.
A luminescent tris (2-thenoyltrifluoroacetonato) europium (III) complex covalently linked to a 1, 10-phenanthroline-functionalised sol-gel glass.
Binnemans K, et al.
Journal of Materials Chemistry, 14(2), 191-195 (2004)



全球贸易项目编号

货号GTIN
33510-5G04061826738894
33510-25G04061835365678