39405
4-(二甲氨基)吡啶
purum, ≥98.0% (NT)
别名:
N,N-二甲基-4-吡啶胺, DMAP
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关于此项目
经验公式（希尔记法）:
C7H10N2
化学文摘社编号:
分子量:
122.17
UNSPSC Code:
12352005
NACRES:
NA.22
PubChem Substance ID:
EC Number:
214-353-5
Beilstein/REAXYS Number:
110354
MDL number:
Assay:
≥98.0% (NT)
Form:
crystals, pellets
grade
purum
Quality Level
assay
≥98.0% (NT)
form
crystals, pellets
mp
108-110 °C (lit.), 111-114 °C
solubility
methanol: 0.1 g/mL, clear, colorless to almost colorless
functional group
amine
SMILES string
CN(C)c1ccncc1
InChI
1S/C7H10N2/c1-9(2)7-3-5-8-6-4-7/h3-6H,1-2H3
InChI key
VHYFNPMBLIVWCW-UHFFFAOYSA-N
General description
4-（二甲基氨基）吡啶通常用作胺、醇、烯醇化物和酚的酰化催化剂。它也可用于羧酸的酯化。众所周知，它在非极性溶剂中有良好的催化活性。
Application
4-（二甲基氨基）吡啶可用于：
- 作为水溶性金纳米颗粒制备中的封端剂
- 作为环氧单体聚合的引发剂
- 作为无电镀制备催化用金纳米颗粒的助剂
- 通过γ,δ-不饱和羧酸的碘内酯化制备γ-和δ-内酯的催化剂。
酰化反应的高效催化剂
Other Notes
Hypernucleophilic acylation catalyst.
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Danger
Hazard Classifications
Acute Tox. 2 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 1
target_organs
Nervous system
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
flash_point_f
255.2 °F
flash_point_c
124 °C
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
E.F. Scriben
Chemical Society Reviews, 13, 129-129 (1983)
Hoefle, G., et al.
Angewandte Chemie (International Edition in English), 90, 602-602 (1978)
Giovanna Cutrone et al.
Carbohydrate polymers, 223, 115085-115085 (2019-08-21)
Nanoparticles made of metal-organic frameworks (nanoMOFs) are becoming of increasing interest as drug carriers. However, engineered coatings such as poly(ethylene glycol) (PEG) based ones are required to prevent nanoMOFs recognition and clearance by the innate immune system, a prerequisite for
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 39405-10G | 04061831982190 |
| 39405-1KG | 04061826714614 |
| 39405-250G | 04061831982206 |
| 39405-50G | 04061831982213 |