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Merck
CN

471283

三乙基胺

≥99.5%, liquid

别名:

N,N-二乙基乙胺

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关于此项目

线性分子式:
(C2H5)3N
化学文摘社编号:
分子量:
101.19
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352116
EC Number:
204-469-4
MDL number:
Beilstein/REAXYS Number:
605283
Assay:
≥99.5%
Bp:
88.8 °C (lit.)
Vapor pressure:
51.75 mmHg ( 20 °C)
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产品名称

三乙基胺, ≥99.5%

vapor density

3.5 (vs air)

vapor pressure

51.75 mmHg ( 20 °C)

assay

≥99.5%

form

liquid

autoignition temp.

593 °F

expl. lim.

8 %

impurities

≤0.1% (Karl Fischer)

refractive index

n20/D 1.401 (lit.)

pH

12.7 (15 °C, 100 g/L)

bp

88.8 °C (lit.)

mp

−115 °C (lit.)

solubility

water: soluble 112 g/L at 20 °C

density

0.726 g/mL at 25 °C (lit.)

functional group

amine

storage temp.

room temp

SMILES string

CCN(CC)CC

InChI

1S/C6H15N/c1-4-7(5-2)6-3/h4-6H2,1-3H3

InChI key

ZMANZCXQSJIPKH-UHFFFAOYSA-N

General description

三乙胺(TEA, Et3N)是一种脂肪族胺。将它添加到基质辅助激光解吸/电离(MALDI)基质中,可在MALDI质谱(MS)成像过程中为透明的液体基质提供增强的空间分辨能力。一种用于测定活性药物成分中的三乙胺的顶空气相色谱(GC)过程已被报道。在一定密度和温度范围内三乙胺蒸汽的粘度系数已得到测量。

Application

三乙胺已用于以下合成过程:
  • 5′-二甲氧基三苯甲基-5-(呋喃-2-基)-2′-脱氧尿苷
  • 3′-(2-氰乙基)二异丙基-5′-二甲氧基三苯甲基-5-(呋喃-2-基)-2'-脱氧尿苷
  • 聚乙胺600-β-环糊精(PEI600-β-CyD)
它还可通过甘油和碳酸二甲酯(DMC)之间的酯交换反应用作制备二碳酸甘油酯的均相催化剂。

Packaging

18 L封闭钢桶封装;100 mL、500 mL、2 L、6×500 mL、4 L玻璃瓶封装;200 L Kilo-Lab®钢瓶封装

Legal Information

Kilo-Lab is a registered trademark of Merck KGaA, Darmstadt, Germany


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signalword

Danger

target_organs

Respiratory system

存储类别

3 - Flammable liquids

flash_point_f

12.2 °F - closed cup

flash_point_c

-11 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A - STOT SE 3

法规信息

危险化学品

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分析证书(COA)

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Nicholas J Greco et al.
Nature protocols, 2(2), 305-316 (2007-04-05)
We describe procedures for the synthesis of a fluorescent pyrimidine analog and its site-specific incorporation into a DNA oligomer. The 5'-protected and 3'-activated nucleoside 4 is synthesized in three steps with an overall yield of 40%. Site-specific incorporation into a
Synthesis of glycerol 1,2-carbonate by transesterification of glycerol with dimethyl carbonate using triethylamine as a facile separable homogeneous catalyst.
Ochoa-Gomez JR, et al.
Green Chemistry, 14(12), 3368-3376 (2012)
The viscosity of triethylamine vapor at low densities and in the saturated vapor phase.
Teske V, et al.
Fluid Phase Equilibria, 293(2), 190-195 (2010)



全球贸易项目编号

货号GTIN
471283-100ML04061837548833
471283-2.5L04061837548840
471283-4L04061832359731
471283-4X100ML04061832359748
471283-18L04061832359717
471283-200L04061838161710
471283-2L04061832359724
471283-4X4L04061832359755
471283-500ML04061837548871
471283-6X500ML04061837548895