86868
Tetrabutylammonium hydrogen sulfate
≥99.0% (T), crystals
别名:
Tetrabutylammonium hydrogen sulfate
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关于此项目
线性分子式:
(CH3CH2CH2CH2)4N(HSO4)
化学文摘社编号:
分子量:
339.53
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
251-068-5
MDL number:
Beilstein/REAXYS Number:
3599663
Assay:
≥99.0% (T)
Form:
crystals
Solubility:
H2O: soluble 10 % (w/v), clear, colorless
产品名称
四丁基硫酸氢铵, puriss., ≥99.0% (T)
grade
puriss.
Quality Level
assay
≥99.0% (T)
form
crystals
reaction suitability
core: ammonium
mp
169-173 °C
solubility
H2O: soluble 10 % (w/v), clear, colorless
functional group
amine
SMILES string
OS([O-])(=O)=O.CCCC[N+](CCCC)(CCCC)CCCC
InChI
1S/C16H36N.H2O4S/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;1-5(2,3)4/h5-16H2,1-4H3;(H2,1,2,3,4)/q+1;/p-1
InChI key
SHFJWMWCIHQNCP-UHFFFAOYSA-M
General description
季铵盐四丁基铵是一种相转移试剂。
Application
四丁基硫酸氢铵可用于以下研究：
- 作为 β-氨基醇和 1，2-二醇合成过程中的催化剂。
- 作为用于合成不对称醚的相转移催化剂。
- 构成用于高效液相色谱（HPLC）分析的流动相。
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signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 2
flash_point_f
348.1 °F - closed cup
flash_point_c
175.6 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Gloves
Polyesters bearing furan moieties: IV. Solution and interfacial polycondensation of 2, 2'-bis (5-chloroformyl-2-furyl) propane with various diols and bisphenols.
Gharbi S, et al.
European Polymer Journal, 36(3), 463-472 (2000)
Phase-transfer synthesis of monoalkyl ethers of oligoethylene glycols.
Gibson T.
The Journal of Organic Chemistry, 45(6), 1095-1098 (1980)
Tetrabutylammonium bisulfate: a new effective catalyst for the hydrolysis of aziridines or epoxides.
Ren-Hua Fan et al.
Organic & biomolecular chemistry, 1(9), 1565-1567 (2003-08-21)
Bu4NHSO4 (TBAHS) is an effective catalyst for the hydrolysis of aziridines and epoxides under mild and non-metal conditions to give the corresponding beta-amino alcohols and 1,2-diols in high yields. The catalyst can be recycled.
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 86868-100G | 04061835252947 |
| 86868-500G | 04061835252961 |
| 86868-25G | 04061835252954 |