主要文件

查看所有文档

936685

Grubbs Catalyst^® M102

Name: Grubbs Catalyst<SUP>&#174;</SUP> M102
Brand: SIAL

solid

别名:

Grubbs Catalyst^® M102, Benzylidene-bis(tricyclohexylphosphine)dichlororuthenium, Bis(tricyclohexylphosphine)benzylidine ruthenium(IV) dichloride ChemBeads, Dichloro(benzylidene)bis(tricyclohexylphosphine)ruthenium(II) ChemBeads, Grubbs Catalyst^® 1st Generation ChemBeads, Grubbs Catalyst^® M1a (C823) ChemBeads

登录查看组织和合同定价。

选择尺寸

变更视图

关于此项目

经验公式（希尔记法）:

C₄₃H₇₂Cl₂P₂Ru

化学文摘社编号:

172222-30-9

分子量:

822.96

MDL number:

MFCD01074452

UNSPSC Code:

12352103

NACRES:

NA.21

Form:

solid ()

技术服务

需要帮助？我们经验丰富的科学家团队随时乐意为您服务。

让我们为您提供帮助

属性

产品名称

Grubbs Catalyst^® M102,

Quality Level

100

product line

ChemBeads

form

solid ()

composition

4-6 wt% loading of catalyst

reaction suitability

reagent type: catalyst
core: ruthenium
reaction type: Ring-Opening Polymerization

greener alternative product characteristics

Waste Prevention
Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

153 °C (dec.)

greener alternative category

Aligned

SMILES string

Cl[Ru]([P](C1CCCCC1)(C2CCCCC2)C3CCCCC3)([P](C4CCCCC4)(C5CCCCC5)C6CCCCC6)(Cl)=CC7=CC=CC=C7, C[Ph].P(C1CCCCC1)(C2CCCCC2)C3CCCCC3.P(C4CCCCC4)(C5CCCCC5)C6CCCCC6.Cl.Cl.[Ru]

InChI

1S/2C18H33P.C7H6.2ClH.Ru/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-7-5-3-2-4-6-7;;;/h2*16-18H,1-15H2;1-6H;2*1H;

InChI key

AULHKSXXVKDNBT-UHFFFAOYSA-N

说明

General description

ChemBeads glass beads coated with Grubbs Catalyst^® M102.

We are committed to bringing you Greener Alternative Products, which adhere to one or more of the 12 Principles of Greener Chemistry. ChemBeads are advanced solid-coated beads for high-throughput experimentation in various chemical applications. They enable precise dispensing of solid reagents, allowing researchers to conduct reactions with minimal material use, thus supporting waste prevention and catalysis principles while ensuring accuracy and reproducibility. This technology enhances efficiency and streamlines experimental processes in chemistry. Click here for more information.

Application

First metathesis catalyst to be widely used in organic synthesis. Useful for acyclic diene metathesis polymerization (ADMET), Ring-Opening Metathesis Polymerization (ROMP) of strained cyclic olefins, ring opening metathesis (ROM), olefin cross metathesis (CM) and ring closing metathesis (RCM) of terminal olefins under a variety of reactions conditions.
ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.
For larger scale uses, product also available in powdered form (579726)

Features and Benefits

Grubbs Catalyst® Technology for Olefin Metathesis by Aldrich
High-Throughput Reaction Screening with Nanomoles of Solid Reagents Coated on Glass Beads
Versatile Methods to Dispense Sub-Milligram Quantities of Solids using Chemical Coated Beads for High-Throughput Experimentation
ChemBead Enabled High-Throughput Cross-Electrophile Coupling Reveals a New Complementary Ligand

Legal Information

Grubbs Catalyst 7578

Grubbs Catalyst is a registered trademark of Umicore AG & Co. KG

pictograms

GHS02

signalword

Warning

hcodes

H228

pcodes

P210 - P240 - P241 - P280 - P370 + P378

Hazard Classifications

Flam. Sol. 2

存储类别

4.1B - Flammable solid hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c