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Merck
CN

940089

RuPhos Pd G2 Chembeads

greener alternative

solid

别名:

2nd Generation RuPhos Precatalyst ChemBeads, Chloro(2-dicyclohexylphosphino-2′,6′-diisopropoxy-1,1′-biphenyl)[2-(2′-amino-1,1′-biphenyl)]palladium(II) ChemBeads, RuPhos-Pd-G2 ChemBeads

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关于此项目

经验公式(希尔记法):
C42H53ClNO2PPd
化学文摘社编号:
分子量:
776.72
UNSPSC Code:
12352100
NACRES:
NA.21
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产品名称

RuPhos Pd G2 Chembeads,

Quality Level

product line

ChemBeads

form

solid

composition

, 4-6 wt. % (loading)

reaction suitability

reagent type: catalyst

greener alternative product characteristics

Waste Prevention
Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

greener alternative category

SMILES string

CC(OC(C=CC=C1OC(C)C)=C1C(C=CC=C2)=C2P(C3CCCCC3)C4CCCCC4)C.Cl[Pd]5C6=CC=CC=C6C7=CC=CC=C7N5

InChI

InChI=1S/C30H43O2P.C12H10N.ClH.Pd/c1-22(2)31-27-19-13-20-28(32-23(3)4)30(27)26-18-11-12-21-29(26)33(24-14-7-5-8-15-24)25-16-9-6-10-17-25;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;;/h11-13,18-25H,5-10,14-17H2,1-4H3;1-6,8-9H,13H2;1H;/q;;;+1/p-1

InChI key

VPDRBFBKNSFRSS-UHFFFAOYSA-M

General description

The ChemBeads product of RuPhos Pd G2, a second generation (G2) precatalyst in which phenethylamine based backbone of the (G1) complex is substituted with a biphenyl-based ligand. Product participates in various palladium catalyzed cross-coupling reactions, C-C, C-N, and C-O bond formation reactions and Suzuki-Miyaura coupling reactions. It generates active Pd catalyst at room temperature in the presence of weak phosphate or carbonate bases.. Loaded on glass beads for use in high-throughput expermentation (HTE).
We are committed to bringing you Greener Alternative Products, which adhere to one or more of the 12 Principles of Greener Chemistry. ChemBeads are advanced solid-coated beads for high-throughput experimentation in various chemical applications. They enable precise dispensing of solid reagents, allowing researchers to conduct reactions with minimal material use, thus supporting waste prevention and catalysis principles while ensuring accuracy and reproducibility. This technology enhances efficiency and streamlines experimental processes in chemistry. Click here for more information.

Application

RuPhos Pd G2 may be employed as precatalyst in the preparation of fluoro-substituted diazatetracenes and diazapentacenes, via Pd-catalyzed aryl amination reaction. (26248605)

ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.

For general uses, product is also available in powdered form (753246)


存储类别

13 - Non Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

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全球贸易项目编号

货号GTIN
940089-1G04065272210140