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Merck
CN

T19526

四甲基氯化铵

reagent grade, ≥98%

别名:

TMA

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关于此项目

线性分子式:
(CH3)4N(Cl)
化学文摘社编号:
分子量:
109.60
UNSPSC Code:
12352100
NACRES:
NA.21
PubChem Substance ID:
EC Number:
200-880-8
Beilstein/REAXYS Number:
3911201
MDL number:
Assay:
≥98%
Grade:
reagent grade
Form:
solid
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grade

reagent grade

Quality Level

assay

≥98%

form

solid

reaction suitability

core: ammonium

mp

>300 °C (lit.)

functional group

amine

SMILES string

[Cl-].C[N+](C)(C)C

InChI

1S/C4H12N.ClH/c1-5(2,3)4;/h1-4H3;1H/q+1;/p-1

InChI key

OKIZCWYLBDKLSU-UHFFFAOYSA-M

General description

四甲基氯化铵是一种季铵盐,由于其热稳定性和对强碱水溶液或亲核试剂的耐受性,通常用作催化剂。

Application

四甲基氯化铵与 N-羟基邻苯二甲酰亚胺和氧杂蒽酮可作为碳氢化合物有氧氧化生成相应含氧化合物的高效氯化物催化体系。它也可作为相转移催化剂,通过活性芳基氯化物与氟化钾在固-液相中的选择性氯/氟交换反应合成芳基氟化物。


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signalword

Danger

Hazard Classifications

Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Aquatic Chronic 2 - Skin Irrit. 2 - STOT SE 1 Oral

target_organs

Central nervous system

存储类别

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges



历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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A free radical process for oxidation of hydrocarbons promoted by nonmetal xanthone and tetramethylammonium chloride under mild conditions.
Du Z, et al.
Tetrahedron Letters, 50(15), 1677-1680 (2009)
Tetramethylammonium chloride as a selective and robust phase transfer catalyst in a solid?liquid halex reaction: the role of water.
Sasson Y, et al.
Chemical Communications (Cambridge, England), 3, 297-298 (1996)
Min Bum Park et al.
Journal of the American Chemical Society, 135(6), 2248-2255 (2012-11-29)
A solid understanding of the molecular-level mechanisms responsible for zeolite crystallization remains one of the most challenging issues in modern zeolite science. Here we investigated the formation pathway for high-silica LTA zeolite crystals in the simultaneous presence of tetraethylammonium (TEA(+))



全球贸易项目编号

货号GTIN
T19526-5G04061837338533
T19526-100G04061837338496
T19526-500G04061837338519