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Merck
CN

06203

氢氧化钠

puriss., meets analytical specification of Ph. Eur., BP, NF, E524, 98-100.5%, pellets

别名:

‘苛性钠’

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关于此项目

线性分子式:
NaOH
化学文摘社编号:
分子量:
40.00
PubChem Substance ID:
UNSPSC Code:
12352302
NACRES:
NA.21
EC Number:
215-185-5
MDL number:
Assay:
98-100.5%
Vapor pressure:
<18 mmHg ( 20 °C), 3 mmHg ( 37 °C)
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vapor density

>1 (vs air)

Quality Level

vapor pressure

<18 mmHg ( 20 °C), 3 mmHg ( 37 °C)

grade

puriss.

assay

98-100.5%

form

pellets

quality

meets analytical specification of Ph. Eur., BP, NF, E524

impurities

≤0.0005% total nitrogen (N), ≤0.002% heavy metals (as Pb), ≤0.5% Na2CO3

mp

318 °C (lit.)

solubility

water: soluble 1260 g/L at 20 °C

density

2.13 g/cm3 at 20 °C

anion traces

chloride (Cl-): 0.002%, phosphate (PO43-): 0.001%, silicate (as SiO2): 0.01%, sulfate (SO42-): 0.003%

cation traces

Al: 0.001%, As: 0.0002%, Ca: 0.001%, Fe: 0.001%, Hg: 0.0001%, K: 0.1%, Pb: 0.00005%

SMILES string

[OH-].[Na+]

InChI

1S/Na.H2O/h;1H2/q+1;/p-1

InChI key

HEMHJVSKTPXQMS-UHFFFAOYSA-M

General description

氢氧化钠,也称为碱液和苛性钠,是一种强碱,作为中和剂广泛用于化学工业、造纸、石油炼制、清洁化合物和下水道清洁剂。

Application

氢氧化钠可用作:
  • 试剂,在金催化下甘油选择性氧化成甘油酸。
  • 催化剂,用于醇与氢硅烷的交叉脱氢偶联,以合成硅醚。
  • 碱,用于芳基卤化物和炔的无过渡金属 Sonogashira 型偶联,以 PEG 为相转移剂合成炔酮。



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pictograms

Corrosion

signalword

Danger

hcodes

Hazard Classifications

Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1A

存储类别

8B - Non-combustible corrosive hazardous materials

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

危险化学品

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历史批次信息供参考:

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Chemoselective, solvent-free aldol condensation reaction.
Raston CL and Scott JL.
Green Chemistry, 2(2), 49-52 (2000)
M A Roberts et al.
Analytical chemistry, 69(11), 2035-2042 (1997-06-01)
This report describes a UV laser photoablation method for the production of miniaturized liquid-handling systems on polymer substrate chips. The fabrication of fluid channel and reservoir networks is accomplished by firing 200 mJ pulses from an UV excimer laser at
Kinetics of sodium borohydride direct oxidation and oxygen reduction in sodium hydroxide electrolyte: Part I. BH4- electro-oxidation on Au and Ag catalysts.
Chatenet M, et al.
Electrochimica Acta, 51(25), 5459-5467 (2006)



全球贸易项目编号

货号GTIN
06203-1KG04061838645906
06203-4X5KG04061838645913
06203-5KG04061838645920
06203-6X1KG04061833635896
06203-288X1KG04061833691687