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Merck
CN

209139

硝酸银

ACS reagent, ≥99.0%

别名:

硝酸银(I)盐

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关于此项目

线性分子式:
AgNO3
化学文摘社编号:
分子量:
169.87
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
231-853-9
MDL number:
Assay:
≥99.0%
Grade:
ACS reagent
Form:
solid
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grade

ACS reagent

Quality Level

vapor density

5.8 (vs air)

assay

≥99.0%

form

solid

reaction suitability

reagent type: catalyst
core: silver

clarity of soln

passes test

impurities

Free acid, passes test, ≤0.01% not HCl pptd.

mp

212 °C (dec.) (lit.)

anion traces

chloride (Cl-): ≤5 ppm, sulfate (SO42-): ≤0.002%

cation traces

Cu: ≤2 ppm, Fe: ≤2 ppm, Pb: ≤0.001%

SMILES string

[O-][N+]([O-])=O.[Ag+]

InChI

1S/Ag.NO3/c;2-1(3)4/q+1;-1

InChI key

SQGYOTSLMSWVJD-UHFFFAOYSA-N

General description

硝酸银,又称硝酸银(I)盐,是一种无臭、无色或白色的多用途无机化合物,因其具有硬化、脱水和硬化的特性而被广泛用作氧化剂和烧灼剂。它通常用作有机硅烷水解氧化的催化剂,导致生产高产氢率和有机硅醇。

Application

硝酸银可用作催化剂:      
  • 用于苯衍生物的 Friedel-Crafts 酰化,以合成相应的酮类。     
  • 有机硅烷的水解氧化,以产生氢。

它可用于制备一些负载酸催化剂,以进行各种有机转化。例如:      
  • 基于 AgNO3–SiO2 的催化剂用于进行螺环化脱芳反应。      
  • 聚苯胺-AgNO3-PTSA(对甲苯磺酸)催化剂用于通过芳香醛、芳香胺和环己酮的三组分曼尼希反应合成抗-β-氨基酮。

AgNO3 也用作前体盐来合成银纳米颗粒。


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signalword

Danger

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Ox. Sol. 2 - Repr. 1B - Skin Corr. 1A

存储类别

5.1B - Oxidizing hazardous materials

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

危险化学品
易制爆化学品

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Catalytic hydrogen evolution from hydrolytic oxidation of organosilanes with silver nitrate catalyst
Teo AKL and Fan WY
Royal Society of Chemistry Advances, 4(71), 37645-37648 (2014)
Hongyan Yang et al.
Antibiotics (Basel, Switzerland), 9(11) (2020-11-01)
Antimicrobial resistance is currently an important concern, but there are few data on the co-presence of metal and antibiotic resistance in potentially pathogenic Escherichia coli entering the food chain from pork, which may threaten human health. We have examined the
D D Songstad et al.
Plant cell reports, 7(4), 262-265 (1988-06-01)
The effect of the ethylene antagonists norbornadiene and silver nitrate and the ethylene precursor l-aminocyclopropane-l-carboxylic acid (ACC) on Zea mays plant regeneration was studied. A 12-fold increase in plant regeneration, as measured by number of plants obtained per gram fresh



全球贸易项目编号

货号GTIN
209139-100G04061837768408
209139-25G04061837768422
209139-500G04061837768439