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Merck
CN

209198

硫酸铜 五水合物

ACS reagent, ≥98.0%

别名:

Cupric sulfate 五水合物, 硫酸,铜(II)盐(1:1)五水合物

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关于此项目

线性分子式:
CuSO4 · 5H2O
化学文摘社编号:
分子量:
249.69
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
231-847-6
MDL number:
Assay:
≥98.0%, 98.0-102.0% (ACS specification)
Grade:
ACS reagent
Form:
crystals
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grade

ACS reagent

vapor pressure

7.3 mmHg ( 25 °C)

assay

≥98.0%, 98.0-102.0% (ACS specification)

form

crystals

reaction suitability

reaction type: click chemistry, reagent type: catalyst
core: copper

pH

3.5-4.5 (20 °C, 50 g/L)

mp

110 °C (dec.) (lit.)

anion traces

chloride (Cl-): ≤0.001%

cation traces

Ca: ≤0.005%, Fe: ≤0.003%, K: ≤0.01%, Na: ≤0.02%, Ni: ≤0.005%

SMILES string

O.O.O.O.O.[Cu++].[O-]S([O-])(=O)=O

InChI

1S/Cu.H2O4S.5H2O/c;1-5(2,3)4;;;;;/h;(H2,1,2,3,4);5*1H2/q+2;;;;;;/p-2

InChI key

JZCCFEFSEZPSOG-UHFFFAOYSA-L

General description

五水硫酸铜(II)是一种常用的路易斯酸催化剂,用于促进酸催化的有机转化。它也可与其他混合氧化剂共同组成有效的氧化还原催化剂。

Application

五水硫酸铜(II)可用作催化剂:      
  • 在乙酸酐环境下,进行醇和酚的乙酰化反应。      
  • 通过酰胺与炔基溴的分子内偶联合成多种酰胺。

还可以用作模板,以乙烯基吡啶和甲基丙烯酸为功能单体合成铜(II)离子印迹聚合物。该聚合物用于通过火焰原子吸收光谱法定量 Cu2+ 离子。

Features and Benefits

CuSO4.5H2O 是一种经济、安全的催化剂,可用于各种有机转化。它也可以回收并在另一个反应中重复使用。


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signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1

flash_point_f

Not applicable

flash_point_c

Not applicable

存储类别

11 - Combustible Solids



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Wei Zhao et al.
Dalton transactions (Cambridge, England : 2003), (8)(8), 1509-1517 (2005-04-13)
Three novel metal-organic frameworks (MOFs), [Cu(1)SO4].H2O (4), [Cu2(2)2(SO4)2].4H2O (5) and [Cu(3)(H2O)]SO4.5.5H2O (6), were obtained by hydrothermal reactions of CuSO4.5H2O with the corresponding ligands, which have different flexibility. The structures of the synthesized complexes were determined by single-crystal X-ray diffraction analyses.
Copper (II) sulfate pentahydrate (CuSO4. 5H2O): a green catalyst for solventless acetylation of alcohols and phenols with acetic anhydride.
Heravi MM, et al.
Journal of the Brazilian Chemical Society, 17(5), 1045-1047 (2006)
Damijana Urankar et al.
Journal of combinatorial chemistry, 10(6), 981-985 (2008-10-17)
Azoamides, previously established as bioactive intracellular GSH-depleting agents, were decorated with a terminal alkyne moiety to 4 and then were transformed, by copper(I)-catalyzed azide-alkyne cycloaddition (CuAAC), into different ligand-arm functionalized azoamides 6. Azides 5 having ligand-arms amenable for binding to



全球贸易项目编号

货号GTIN
209198-100G04061837768453
209198-2.5KG04061835346585
209198-5G04061837768484
209198-12KG04061838770592
209198-250G04061837768460
209198-25KG04061833636473
209198-500G04061837768477