212946
氯化亚铜
reagent grade, 97%
别名:
一氯化铜
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关于此项目
线性分子式:
CuCl
化学文摘社编号:
分子量:
99.00
NACRES:
NA.55
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
231-842-9
MDL number:
Assay:
97%
Grade:
reagent grade
Form:
powder
Solubility:
dimethyl sulfide: partially soluble(lit.), water: insoluble(lit.)
grade
reagent grade
Quality Level
vapor pressure
1.3 mmHg ( 546 °C)
assay
97%
form
powder
reaction suitability
reagent type: catalyst
core: copper
pH
5 (20 °C, 50 g/L)
bp
1490 °C (lit.)
mp
430 °C (lit.)
solubility
dimethyl sulfide: partially soluble(lit.), water: insoluble(lit.)
SMILES string
Cl[Cu]
InChI
1S/ClH.Cu/h1H;/q;+1/p-1
InChI key
OXBLHERUFWYNTN-UHFFFAOYSA-M
General description
Cu 在 CuCl 中以 + 1（亚铜）价态存在。CuCl 是一种具有宽带隙的半导体。由于其晶格与硅相似，因此是硅光电器件的一种很有前途的候选材料。参与格氏试剂的各种反应。
Application
氯化铜 (I)（氯化亚铜，CuCl）已用于合成 7-（（叔 -丁基二甲基硅基）氧）七-2,4-二炔-1-醇。CuCl 可用于环共轭二烯的立体定向合成。它可用作研究氯化铜络合物在水热溶液中稳定性的反应物。
作为自由基反应（如 α,β-不饱和酮的锡氢化作用）的引发剂表现出独特的性质。
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Danger
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Irrit. 2
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Copper (I) chloride-mediated intramolecular coupling of vinyltrimethylstannane and vinyl halide functions.
Piers E and Wong T.
The Journal of Organic Chemistry, 58(14), 3609-3610 (1993)
Copper (I) Chloride.
Bertz SH, et al.
e-EROS Encyclopedia of Reagents for Organic Synthesis. (2007)
Experimental study of copper (I) chloride complexing in hydrothermal solutions at 40 to 300 ?C and saturated water vapor pressure.
Xiao Z, et al.
Geochimica et Cosmochimica Acta, 62(17), 2949-2964 (1998)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| F4537-50UG | 04061833617793 |
| 212946-2KG | 04061838772510 |
| 212946-25G | 04061838772503 |
| 212946-500G | 04061835276608 |