vapor pressure
1 hPa ( 748 °C)
Quality Level
product line
ReagentPlus®
assay
≥99%
form
powder
pH
7 (20 °C, 10 g/L)
mp
550 °C (lit.)
SMILES string
[Li+].[Br-]
InChI
1S/BrH.Li/h1H;/q;+1/p-1
InChI key
AMXOYNBUYSYVKV-UHFFFAOYSA-M
General description
LiBr/三甲基氯硅烷试剂参与醇向溴化物的转换。
Application
溴化锂（LiBr）可用作以下研究的催化剂：
- 通过无溶剂二硫代缩醛反应将（芳族-和α,β-不饱和）醛转化为二硫代缩醛。
- 通过羰基化合物与活性亚甲基化合物的缩合反应合成烯烃。
- β-氨基醇的绿色合成。
- 通过使用LiBr/硝酸铈铵（CAN）试剂系统（作为Br+ 离子来源）进行芳族化合物的化学和区域选择性溴化。
Other Notes
Legal Information
Redi-Dri is a trademark of Sigma-Aldrich Co. LLC
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
Still not finding the right product?
Explore all of our products under 溴化锂
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1
存储类别
11 - Combustible Solids
wgk
WGK 2
flash_point_f
No data available
flash_point_c
No data available
Lithium Bromide, an Inexpensive and Efficient Catalyst for Opening of Epoxide Rings by Amines at Room Temperature under Solvent-Free Condition.
Chakraborti AK, et al.
European Journal of Organic Chemistry, 2004(17), 3597-3600 (2004)
Lithium bromide-catalyzed highly chemoselective and efficient dithioacetalization of α,β-unsaturated and aromatic aldehydes under solvent-free conditions.
Firouzabadi H, et al.
Synthesis, 58-60 (1999)
An efficient chemo and regioselective oxidative nuclear bromination of activated aromatic compounds using lithium bromide and ceric ammonium nitrate.
Roy SC, et al.
Tetrahedron Letters, 42(39), 6941-6942 (2001)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 213225-2KG | 04061838772633 |
| 213225-500G | 04061837632600 |
| 213225-100G | 04061837632594 |