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Merck
CN

244260

氢溴酸

ACS reagent, 48%

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关于此项目

经验公式(希尔记法):
HBr
化学文摘社编号:
分子量:
80.91
UNSPSC Code:
12352106
NACRES:
NA.21
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3587158
Assay:
47.0-49.0% (ACS specification), 48%
Form:
liquid
Grade:
ACS reagent
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grade

ACS reagent

Quality Level

vapor density

2.8 (vs air)

vapor pressure

320 psi ( 21.1 °C), 8 mmHg ( 25 °C)

description

48% aqueous HBr

assay

47.0-49.0% (ACS specification), 48%

form

liquid

impurities

≤5 ppm Heavy Metals

ign. residue

≤0.002%

solubility

water: soluble at 20 °C

density

1.49 g/mL at 25 °C (lit.)

anion traces

SO42- and SO32-: ≤0.003%, chloride (Cl-): ≤0.05%, iodide (I-): ≤0.003%, phosphate (PO43-): ≤0.001%

cation traces

Fe: ≤1 ppm, Se: ≤0.01 ppm, heavy metals: ≤5 ppm (by ICP-OES)

SMILES string

Br

InChI

1S/BrH/h1H

InChI key

CPELXLSAUQHCOX-UHFFFAOYSA-N

General description

氢溴酸是一种强酸,可作为溴化试剂用于烯烃、炔烃和酮的亲电和自由基溴化。

Application

氢溴酸可作为溴化剂用于:
  • 用于苯胺到溴代苯胺的区域选择性溴化。
  • 烯烃、炔烃和酮氧化溴化成相应的二溴化烷烃、二溴化烯烃和 α-溴酮。
它也可作为将醇有氧光氧化成相应羧酸的催化剂。

Other Notes

ACS规格与产品438065相同


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pictograms

CorrosionExclamation mark

signalword

Danger

target_organs

Respiratory system

存储类别

8B - Non-combustible corrosive hazardous materials

flash_point_f

Not applicable

flash_point_c

Not applicable

Hazard Classifications

Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1A - STOT SE 3

法规信息

危险化学品

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Hydrobromic acid-catalyzed Friedel-Crafts type reactions of naphthols.
Xu C, et al.
Royal Society of Chemistry Advances, 4(4), 1559-1562 (2014)
Production of cellulose nanocrystals using hydrobromic acid and click reactions on their surface.
Sadeghifar H, et al.
J. Mater. Sci., 46(22), 7344-7355 (2011)
M Y Mirza
Talanta, 27(2), 101-106 (1980-02-01)
The extraction of Pd(II), Rh(III), Ir(III), Au(III) and Pt(IV) from hydrochloric and hydrobromic acid with 5% tri-iso-octylamine solution in carbon tetrachloride has been studied. The gold extract from hydrochloric acid is yellow and absorbs at 325 nm, the palladium compound



全球贸易项目编号

货号GTIN
244260-4X100ML04061837734809
244260-500ML04061825751788
244260-100ML04061825751764
244260-1L04061825751771
244260-500ML-PC04061837734816