31293
硫酸铜 五水合物
puriss. p.a., ACS reagent, reag. ISO, reag. Ph. Eur., 99-102%
别名:
Cupric sulfate 五水合物, 硫酸，铜（II）盐（1：1）五水合物
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关于此项目
线性分子式:
CuSO4 · 5H2O
化学文摘社编号:
分子量:
249.69
MDL number:
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
231-847-6
Assay:
99-102%
Form:
solid
Quality Level
agency
USP/NF, reag. ISO, reag. Ph. Eur.
vapor pressure
7.3 mmHg ( 25 °C)
grade
ACS reagent, puriss. p.a.
assay
99-102%
form
solid
impurities
≤0.001% total nitrogen (N), ≤0.005% in water insoluble matters
pH
3.7-4.5 (20 °C, 5%)
mp
110 °C (dec.) (lit.)
anion traces
chloride (Cl-): ≤10 mg/kg
cation traces
As: ≤0.5 mg/kg, Ca: ≤10 mg/kg, Cd: ≤10 mg/kg, Co: ≤10 mg/kg, Fe: ≤20 mg/kg, K: ≤10 mg/kg, Mg: ≤5 mg/kg, Na: ≤20 mg/kg, Ni: ≤20 mg/kg, Pb: ≤20 mg/kg, Zn: ≤300 mg/kg
SMILES string
O.O.O.O.O.[Cu++].[O-]S([O-])(=O)=O
InChI
1S/Cu.H2O4S.5H2O/c;1-5(2,3)4;;;;;/h;(H2,1,2,3,4);5*1H2/q+2;;;;;;/p-2
InChI key
JZCCFEFSEZPSOG-UHFFFAOYSA-L
General description
五水硫酸铜（II）（CuSO4·5H2O，胆矾）是一种水合铜（II）盐。它能与三脚架配体发生水热反应，产生金属-有机骨架（MOF）。CuSO4·5H2O 与金属铜能够一起催化不同配体臂官能化偶氮酰胺的合成。当加热到560℃以上后，它会分解成CuO。
Application
五水硫酸铜（II）可用于以下研究：
- 在无溶剂条件下作为醇类和酚类乙酰化的催化剂。
- 制备用于Cu-Zn-Sn前体电沉积的电解质，它是制备Cu2ZnSnS4 (CZTS)薄膜所必需的。
- 作为乙醇的脱水反应的催化剂。
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flash_point_c
Not applicable
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1
存储类别
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
Copper (II) Sulfate.
Hoffman RV, et al.
e-EROS Encyclopedia of Reagents for Organic Synthesis. (2001)
Wei Zhao et al.
Dalton transactions (Cambridge, England : 2003), (8)(8), 1509-1517 (2005-04-13)
Three novel metal-organic frameworks (MOFs), [Cu(1)SO4].H2O (4), [Cu2(2)2(SO4)2].4H2O (5) and [Cu(3)(H2O)]SO4.5.5H2O (6), were obtained by hydrothermal reactions of CuSO4.5H2O with the corresponding ligands, which have different flexibility. The structures of the synthesized complexes were determined by single-crystal X-ray diffraction analyses.
Copper (II) sulfate pentahydrate (CuSO4. 5H2O): a green catalyst for solventless acetylation of alcohols and phenols with acetic anhydride.
Heravi MM, et al.
Journal of the Brazilian Chemical Society, 17(5), 1045-1047 (2006)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 31293-100G | 04061826682579 |
| 31293-1KG | 04061835562312 |
| 31293-500G | 04061826682593 |