form
liquid
Quality Level
concentration
0.5 M in THF, 470-600 mmol/L (silver nitrate titration)
density
0.948 g/mL at 25 °C
SMILES string
Cl[Zn]Cl
InChI
1S/2ClH.Zn/h2*1H;/q;;+2/p-2
InChI key
JIAARYAFYJHUJI-UHFFFAOYSA-L
General description
氯化锌溶液是一种无色液体，含有溶于 THF 的氯化锌。其合成已有报道。
Application
以氯化锌水溶液为溶剂，合成了二茂铁芳烃。
它可通过与格氏试剂反应原位生成有机臭氧化物试剂，也可用于催化固相多肽合成中树脂的氯甲基化。
它可通过与格氏试剂反应原位生成有机臭氧化物试剂，也可用于催化固相多肽合成中树脂的氯甲基化。
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signalword
Danger
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Chronic 2 - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
target_organs
Central nervous system, Respiratory system
supp_hazards
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
-4.0 °F - closed cup
flash_point_c
-20 °C - closed cup
法规信息
危险化学品
此项目有
Zinc chloride-catalyzed chloromethylation of resins for solid phase peptide synthesis.
Feinberg RS and Merrifield RB.
Tetrahedron, 30(17), 3209-3212 (1974)
Versatile palladium (II)-catalyzed Negishi coupling reactions with functionalized conjugated alkenyl chlorides.
Peyrat JF, et al.
Tetrahedron Letters, 44(35), 6703-6707 (2003)
Thin-layer electrochemistry of ferrocenylbenzene derivatives: Intramolecular electronic communication.
Wang MCP, et al.
Electrochimica Acta, 53(26), 7720-7725 (2008)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 366374-100ML | 04061831826074 |
| 366374-800ML | 04061837633577 |