73036
氯化锂
puriss. p.a., anhydrous, ≥99.0% (AT)
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关于此项目
线性分子式:
LiCl
化学文摘社编号:
分子量:
42.39
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
231-212-3
MDL number:
Assay:
≥99.0% (AT)
Form:
powder or crystals
vapor pressure
1.33 hPa ( 547 °C)
Quality Level
grade
puriss. p.a.
assay
≥99.0% (AT)
form
powder or crystals
loss
<1% loss on drying, 110°C
pH
5.5-7.5 (25 °C, 50 mg/mL in H2O)
mp
605 °C (lit.)
anion traces
sulfate (SO42-): ≤50 mg/kg
cation traces
Ba: ≤10 mg/kg, Ca: ≤20 mg/kg, Cd: ≤5 mg/kg, Co: ≤5 mg/kg, Cr: ≤5 mg/kg, Cu: ≤5 mg/kg, Fe: ≤5 mg/kg, K: ≤50 mg/kg, Mg: ≤5 mg/kg, Mn: ≤5 mg/kg, Na: ≤50 mg/kg, Ni: ≤10 mg/kg, Pb: ≤5 mg/kg, Zn: ≤5 mg/kg
SMILES string
[Li+].[Cl-]
InChI
1S/ClH.Li/h1H;/q;+1/p-1
InChI key
KWGKDLIKAYFUFQ-UHFFFAOYSA-M
General description
氯化锂（LiCl）是一种锂盐。它参与碱敏感性醛和膦酸盐的Horner-Wadsworth-Emmons反应。 LiCl/N,N-二甲基乙酰胺（DMAc）溶剂体系已被用于溶解纤维素和合成各种纤维素衍生物（纤维素酯、氨基甲酸酯、磺酸酯和醚）。它可以由碳酸锂（Li2CO3）合成。
Application
氯化锂（LiCl）可以与高氯酸反应以合成高氯酸锂。
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signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2
存储类别
13 - Non Combustible Solids
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
Derivatization of cellulose in lithium chloride and N-N-dimethylacetamide solutions.
McCormick CL and Callais PA.
Polymer, 28(13), 2317-2323 (1987)
Horner-wadsworth-emmons reaction: Use of lithium chloride and an amine for base-sensitive compounds.
Blanchette MA, et al.
Tetrahedron Letters, 25(21), 2183-2186 (1984)
Hart WA, et al.
The Chemistry of Lithium, Sodium, Potassium, Rubidium, Cesium and Francium, 355-355 (1973)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 73036-100G-F | 04061832865164 |