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Merck
CN

D137510

N,N-二甲基乙酰胺

ReagentPlus®, 99%

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关于此项目

线性分子式:
CH3CON(CH3)2
化学文摘社编号:
分子量:
87.12
UNSPSC Code:
12352111
NACRES:
NA.21
PubChem Substance ID:
EC Number:
204-826-4
Beilstein/REAXYS Number:
1737614
MDL number:
eCl@ss:
39031204
Assay:
99%
Bp:
164.5-166 °C (lit.)
Vapor pressure:
2 mmHg ( 25 °C), 4 mmHg ( 38 °C)
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vapor density

3 (vs air)

Quality Level

vapor pressure

2 mmHg ( 25 °C), 4 mmHg ( 38 °C)

product line

ReagentPlus®

assay

99%

form

liquid

autoignition temp.

914 °F

expl. lim.

1.8 %, 100 °F, 11.5 %, 160 °F

dilution

(for general lab use)

refractive index

n20/D 1.437 (lit.)

pH

4 (20 °C, 200 g/L)

bp

164.5-166 °C (lit.)

mp

−20 °C (lit.)

density

0.937 g/mL at 25 °C (lit.)

SMILES string

CN(C)C(C)=O

InChI

1S/C4H9NO/c1-4(6)5(2)3/h1-3H3

InChI key

FXHOOIRPVKKKFG-UHFFFAOYSA-N

General description

N,N-二甲基乙酰胺(DMAc)是一种与水混溶的有机溶剂,用于合成苯乙烯、乙烯基树脂、线型聚酯、丙烯酸纤维、塑料、农药和合成革。此外,它还用于粘合剂、薄膜和油漆的生产。它参与过渡金属的脱氢、脱水、卤化、去质子反应和还原羰基化反应。它还可以作为催化剂、促进剂、卤素/烷氧基或羟基/卤素交换介质、还原剂和碱源。

Application

N,N-二甲基乙酰胺可作为溶剂,用于合成:
  • 在 LiCl 环境下下,用微晶纤维素、CaCl2 和 NaH2PO4 合成纤维素-HA(羟磷灰石)。
  • 在 LiCl 环境下从各种碳水化合物和天然生物聚合物木质纤维素合成 5-羟甲基糠醛(HMF)。

它还可用于:
  • 在 Pd 催化下利用分子氧从烯烃中区域选择性合成酮。
  • 作为溶剂和亚甲基源,使用 Cu(OAc)2 催化剂,用于两个咪唑[1,2-a]吡啶的区域选择性链接。

Features and Benefits

N,N-二甲基乙酰胺
  • 对各种底物有很高的溶解能力。
  • 高容量的溶剂化阴离子。

Legal Information

Belle Chemical公司
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany


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pictograms

Health hazardExclamation mark

signalword

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Eye Irrit. 2 - Repr. 1B

存储类别

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 2

flash_point_f

147.2 °F - closed cup

flash_point_c

64 °C - closed cup



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分析证书(COA)

Lot/Batch Number

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André H Gröschel et al.
Nature communications, 3, 710-710 (2012-03-20)
Hierarchical self-assembly offers elegant and energy-efficient bottom-up strategies for the structuring of complex materials. For block copolymers, the last decade witnessed great progress in diversifying the structural complexity of solution-based assemblies into multicompartment micelles. However, a general understanding of what
Nobuhiko Ichihara et al.
Carbohydrate research, 346(15), 2515-2518 (2011-09-17)
6-Azafulleroid-6-deoxy-2,3-di-O-myristoylcellulose (3) was synthesized from 6-azido-6-deoxycellulose (1) by two reaction steps. The myristoylation of compound 1 with myristoyl chloride/pyridine proceeded smoothly to give 6-azido-6-deoxy-2,3-di-O-myristoylcellulose (2) in 97.0% yield. The reaction of compound 2 with fullerene (C(60)) was carried out by
Fatma Kayaci et al.
Nanoscale, 6(17), 10224-10234 (2014-07-25)
Oxygen vacancies (V(O)s) in ZnO are well-known to enhance photocatalytic activity (PCA) despite various other intrinsic crystal defects. In this study, we aim to elucidate the effect of zinc interstitials (Zn(i)) and V(O)s on PCA, which has applied as well



全球贸易项目编号

货号GTIN
D137510-2.5L04061833559673
D137510-4L04061833559680
D137510-18L-CS04061837717000
D137510-1L04061833559666
D137510-20L04061837717017
D137510-500ML04061837226977