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Merck
CN

S9640

四硼酸钠 十水合物

ACS reagent, ≥99.5%

别名:

硼砂 十水合物, 硼酸钠 十水合物

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关于此项目

线性分子式:
Na2B4O7 · 10H2O
化学文摘社编号:
分子量:
381.37
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
215-540-4
MDL number:
Assay:
≥99.5%
Grade:
ACS reagent
Form:
powder or crystals
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grade

ACS reagent

Quality Level

agency

suitable for SM 4500 - NH3

vapor pressure

0.213 hPa ( 20 °C)

assay

≥99.5%

form

powder or crystals

impurities

≤0.005% Insoluble matter

pH

9.15-9.20 (25 °C, 0.01 M in solution)

density

1.73 g/mL at 25 °C (lit.)

anion traces

chloride (Cl-): ≤0.001%, phosphate (PO43-): ≤0.001%, sulfate (SO42-): ≤0.005%

cation traces

Ca: ≤0.005%, Fe: ≤5 ppm, heavy metals (as Pb): ≤0.001%

SMILES string

O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[O-]B1Ob2ob([O-])ob(O1)o2

InChI

1S/B4O7.2Na.10H2O/c5-1-7-3-9-2(6)10-4(8-1)11-3;;;;;;;;;;;;/h;;;10*1H2/q-2;2*+1;;;;;;;;;;

InChI key

CDMADVZSLOHIFP-UHFFFAOYSA-N

General description

十水合四硼酸钠是一种天然存在的材料,可用作许多有机转化的催化剂或添加剂,如内夫反应、克内文纳格尔缩合反应、取代、加成、邻二醇的选择性甲基化和三甲基硅基炔酮的脱硅基化。

Application

十水四硼酸钠可作为催化剂用于:
  • 使用硫醇合成 β-羟基硫化物,对 1,2-环氧化合物进行区域选择性硫解。
  • 硫醇与缺电子烯烃的杂 Michael 加成,以合成相应的 β-加合物。
  • 无溶剂 Biginelli 反应,以合成 3,4-二氢嘧啶-2(1H)-酮。
还可作为添加剂制备具有高介电性能的聚吡咯-硼砂复合材料。

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pictograms

Health hazardExclamation mark

signalword

Danger

Hazard Classifications

Eye Irrit. 2 - Repr. 1B

存储类别

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable



历史批次信息供参考:

分析证书(COA)

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相关内容

This page is intended to make it easier to find the consumables you need based on the analytical method you’re using. Methods included on this page come from the EPA, Standard Methods and ASTM.


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全球贸易项目编号

货号GTIN
S9640-500G04061835349784
S9640-2.5KG04061835349760
S9640-4X2.5KG04061836961619
S9640-25G04061835349777