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Merck
CN

T24007

四甲基硅烷

ACS reagent, NMR grade, ≥99.9%

别名:

TMS

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关于此项目

线性分子式:
Si(CH3)4
化学文摘社编号:
分子量:
88.22
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
EC Number:
200-899-1
Beilstein/REAXYS Number:
1696908
MDL number:
Assay:
≥99.9%
Grade:
ACS reagent
Technique(s):
NMR: suitable
Bp:
26-28 °C (lit.)
Vapor pressure:
11.66 psi ( 20 °C)
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grade

ACS reagent

Quality Level

vapor pressure

11.66 psi ( 20 °C)

assay

≥99.9%

form

liquid

autoignition temp.

842 °F

expl. lim.

0.34-6.3 %

technique(s)

NMR: suitable

evapn. residue

≤0.05%

refractive index

n20/D 1.358 (lit.)

bp

26-28 °C (lit.)

mp

−99 °C (lit.)

density

0.648 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

C[Si](C)(C)C

InChI

1S/C4H12Si/c1-5(2,3)4/h1-4H3

InChI key

CZDYPVPMEAXLPK-UHFFFAOYSA-N

Application

四甲基硅烷可用作:
  • 前体,通过化学气相沉积法合成α-SiC。
  • 反应物,在氯化铝和二氯甲烷环境下由金刚烷合成1,3,5,7-四甲基金刚烷。
  • 溶剂,用于1-辛烯与吗啉的氢胺甲基化。
  • 甲基化试剂,将四氯化锗转化为四甲基锗、三甲基氯化锗、二甲基氯化锗或三氯化甲基锗。


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pictograms

Flame

signalword

Danger

hcodes

Hazard Classifications

Flam. Liq. 1

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

-16.6 °F - closed cup

flash_point_c

-27 °C - closed cup

法规信息

危险化学品

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Tetramethylsilane in synthesis: selective mono-and polymethylations of germanium tetrachloride
Bordeau M, et al.
Organometallics, 1087-1089, 4-4 (1985)
James C Salamanca et al.
Scientific reports, 8(1), 7559-7559 (2018-05-17)
E-cigarette aerosol emission studies typically focus on benchmarking toxicant levels versus those of cigarettes. However, such studies do not fully account for the distinct chemical makeup of e-liquids and their unique properties. These approaches often conclude that there are fewer
Roy E Hoffman
Journal of magnetic resonance (San Diego, Calif. : 1997), 163(2), 325-331 (2003-08-14)
The chemical shift of TMS is commonly assumed to be zero. However, it varies by over 1 ppm for 1H and 4 ppm for 13C and shows a correlation with the physical properties of the solvent. Using the commonly accepted



全球贸易项目编号

货号GTIN
T24007-100G04061837342158
T24007-25G04061837342165