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Merck
CN

33092-U

叔丁基二甲基哇烷基咪唑 溶液

TBDMSIM in DMF, pkg of 10 × 1 mL

别名:

1-(叔丁基二甲基硅烷基)咪唑 溶液

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关于此项目

经验公式(希尔记法):
C9H18N2Si
化学文摘社编号:
分子量:
182.34
UNSPSC Code:
12352200
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description

Silylation reagent

Quality Level

packaging

pkg of 10 × 1 mL

concentration

TBDMSIM in DMF

InChI

1S/C9H18N2Si/c1-9(2,3)12(4,5)11-7-6-10-8-11/h6-8H,1-5H3

InChI key

VUENSYJCBOSTCS-UHFFFAOYSA-N

General description

tert-Butyldimethylsilylimidazole solution is a derivatizing reagent. It is most effective for silylating multiwall carbon nanotubes (MWNT).

Application

It was used to convert oxysterols to tert-butyldimethylsilyl (TBDMSi) ethers for 18O enrichment during oxysterols determination in plasma and liver, using gas/liquid chromatography-mass spectrometry analysis.


signalword

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Aquatic Chronic 3 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 1B - Skin Corr. 1A

存储类别

3 - Flammable liquids

wgk

WGK 2

flash_point_f

71.6 °F - closed cup

flash_point_c

22 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

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Yury Gogotsi
Nanotubes and Nanofibers, 46-46 (2006)
O Breuer et al.
The Journal of biological chemistry, 270(35), 20278-20284 (1995-09-01)
Cholesterol oxidation products (oxysterols) have been detected in many different tissues, often at concentrations 10(3) to 10(4) times lower than cholesterol. This constitutes a considerable risk of quantitation errors, since even a minor oxidation of cholesterol during sample processing would
E.J.Corey and A. Venkateswarlu
Journal of the American Chemical Society, 94, 6190-6190 (1972)