190500
叔丁基二甲基氯硅烷
reagent grade, 97%
别名:
TBDMSCl, 叔丁基(氯)二甲基硅烷, 叔丁基二甲基氯硅烷
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关于此项目
线性分子式:
(CH3)3CSi(CH3)2Cl
化学文摘社编号:
分子量:
150.72
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
EC Number:
242-042-4
Beilstein/REAXYS Number:
505999
MDL number:
Assay:
97%
Form:
solid
grade
reagent grade
Quality Level
assay
97%
form
solid
bp
125 °C (lit.)
mp
86-89 °C (lit.)
SMILES string
CC(C)(C)[Si](C)(C)Cl
InChI
1S/C6H15ClSi/c1-6(2,3)8(4,5)7/h1-5H3
InChI key
BCNZYOJHNLTNEZ-UHFFFAOYSA-N
Application
叔丁基二甲基氯硅烷(TBDMSCl)是一种有机硅化合物，可用作醇、胺、酰胺和各种羧酸的多功能保护试剂。它还用于通过α-溴代硝基烷烃和烯烃制备异噁唑啉N-氧化物。TBDMSCl可作为前体合成Ag/ZnO/石墨烯基纳米复合材料的硅基底，该纳米材料可用于形成有效的制氢光催化体系。
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signalword
Danger
hcodes
Hazard Classifications
Aquatic Chronic 2 - Eye Dam. 1 - Flam. Sol. 1 - Skin Corr. 1A
存储类别
4.1B - Flammable solid hazardous materials
wgk
WGK 2
flash_point_f
71.6 °F - closed cup
flash_point_c
22 °C - closed cup
Roman A Kunetsky et al.
Organic letters, 5(25), 4907-4909 (2003-12-05)
A strategy for the synthesis of isoxazoline-N-oxides (cyclic five-membered nitronates) from primary nitro compounds and olefins is described. The key step of the process involves 1,3-dipolar cycloaddition of corresponding 1-bromosilyl nitronates with alkenes. [reaction: see text]
New approach for the synthesis of isoxazoline-N-oxides
Kunetsky RA, et al.
Organic Letters, 5(25) (2003)
Effective silylation of carboxylic acids under solvent-free conditions with tert-butyldimethylsilyl chloride (TBDMSCL) and triisopropylsilyl chloride (TIPSCL)
Firouzabadi H, et al.
Phosphorus, Sulfur, and Silicon and the Related Elements, 166(1) (2000)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 190500-100G | 04061835554508 |
| 190500-5G | 04061838759856 |
| 190500-1KG | 04061826732021 |
| 190500-25G | 04061838759832 |
| 190500-500G | 04061838759849 |