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177261

DPPF

Name: DPPF
Brand: ALDRICH

97%, powder

Synonym(s):

1,1′-Ferrocenediyl-bis(diphenylphosphine), dppf

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About This Item

Empirical Formula (Hill Notation):

C₃₄H₂₈FeP₂

CAS Number:

12150-46-8

Molecular Weight:

554.38

UNSPSC Code:

12350000

PubChem Substance ID:

24850625

NACRES:

NA.22

MDL number:

MFCD00001422

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Properties

Product Name

DPPF, 97%

Quality Level

200

assay

97%

form

powder

reaction suitability

reaction type: Cross Couplings, reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reagent type: ligand
reaction type: Carbonylations, reagent type: ligand
reaction type: Ene Reaction, reagent type: ligand
reaction type: Heck Reaction, reagent type: ligand
reaction type: Negishi Coupling, reagent type: ligand
reaction type: Sonogashira Coupling, reagent type: ligand
reaction type: Stille Coupling, reagent type: ligand
reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
reaction type: Tsuji-Trost Reaction

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

181-182 °C (dec.) (lit.)

functional group

phosphine

greener alternative category

Aligned,

SMILES string

[Fe].[CH]1[CH][CH][C]([CH]1)P(c2ccccc2)c3ccccc3.[CH]4[CH][CH][C]([CH]4)P(c5ccccc5)c6ccccc6

InChI

1S/2C17H14P.Fe/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;/h2*1-14H;

InChI key

HPXNTHKXCYMIJL-UHFFFAOYSA-N

Description

General description

Novel functionalized furan derivatives were prepared via Pd-phosphine sequential C-C and C-O bond formation.

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Ligand used in a Pd(II)-catalyzed cross-coupling synthesis of oxazepine ring systems.

Ligand for ruthenium-catalyzed greener amine synthesis from amines and alcohols by hydrogen-borrowing.

Ruthenium-Catalyzed N-Alkylation of Amines and Sulfonamides Using Borrowing Hydrogen Methodology

Storage Class

11 - Combustible Solids

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

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Global Trade Item Number

SKU	GTIN
177261-25G	04061833544839
177261-10G	04061838753182
177261-1G	04061838753199
177261-250G	04061833472729