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Merck
CN

10035

Ammonium metatungstate hydrate

≥85% WO3 basis (gravimetric)

Synonym(s):

AMT, Hexaammonium wolframate hydrate, Tungstic acid hexaammonium salt

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About This Item

Linear Formula:
(NH4)6H2W12O40 · xH2O
CAS Number:
Molecular Weight:
2956.30 (anhydrous basis)
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352300
EC Number:
234-733-4
MDL number:
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Quality Level

assay

≥85% WO3 basis (gravimetric)

form

solid

reaction suitability

reagent type: catalyst
core: tungsten

impurities

≤0.005% water-insoluble matter

loss

≤15% loss on ignition

mp

100 °C (dec.) (lit.)

SMILES string

N.N.N.N.N.N.O.O[W]1O[W](O)(=O)(O1)O[W]2(=O)(=O)O[W](O)(=O)(O2)O[W]3(=O)(=O)O[W](O)(=O)(O3)O[W]4(=O)(=O)O[W](O)(=O)(O[W]5(=O)(=O)O[W](O)(=O)(O[W]6(=O)(=O)O[W](O)(O)O6)O5)O4

InChI

1S/6H3N.9H2O.32O.12W/h6*1H3;9*1H2;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;/q;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;6*+1;+2/p-8

InChI key

ZBHPUDGBNLMJQH-UHFFFAOYSA-F

General description

Ammonium metatungstate hydrate is used as a starting material to prepare catalysts for the reduction of NOx. It can also be used as a precursor to synthesize tungsten oxide thin films by chemical vapor deposition method.

Application

  • Effect of morphology properties of NiW catalysts on hydrodesulfurization for individual sulfur compounds in fluid catalytic cracking diesel: This research discusses the influence of ammonium metatungstate hydrate in the preparation of NiW catalysts, focusing on its role in hydrodesulfurization processes (X Tao et al., 2014).
  • Preparation of quaternary tungsten bronze nanoparticles by a thermal decomposition of ammonium metatungstate with oleylamine: This study examines the decomposition pathways of ammonium metatungstate hydrate into metatungstate anions and their applications in creating tungsten bronze nanoparticles (J Choi et al., 2015).


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pictograms

CorrosionExclamation mark

signalword

Danger

hcodes

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1

Storage Class

11 - Combustible Solids

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves



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Daniel Delgado et al.
Dalton transactions (Cambridge, England : 2003), 49(38), 13282-13293 (2020-09-17)
Materials from the WO3-Nb2O5 system, presenting bronze-type crystal structures, display outstanding functional properties for several applications as thermoelectric materials, lithium-ion battery electrodes, or catalysts. In this work, a series of W-Nb-O oxide bronzes have been synthesized by the hydrothermal method
Ze-Da Meng et al.
Nanoscale research letters, 6(1), 459-459 (2011-07-22)
WO3-treated fullerene/TiO2 composites (WO3-fullerene/TiO2) were prepared using a sol-gel method. The composite obtained was characterized by BET surface area measurements, X-ray diffraction, scanning electron microscopy, energy dispersive X-ray analysis, transmission electron microscopy, and UV-vis analysis. A methyl orange (MO) solution
Alessandro Chieregato et al.
ChemSusChem, 8(2), 398-406 (2014-12-10)
Glycerol surplus from biodiesel synthesis still represents a major problem in the biofuel production chain. Meanwhile, those in the acrylic acid market are looking for new processes that are able to offer viable alternatives to propylene-based production. Therefore, acrylic acid



Global Trade Item Number

SKUGTIN
10035-100G04061838663610
10035-500G04061833439869