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112933

Acetanilide

Name: Acetanilide
Brand: ALDRICH

99%

Synonym(s):

N-Phenylacetamide

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About This Item

Linear Formula:

CH₃CONHC₆H₅

CAS Number:

103-84-4

Molecular Weight:

135.16

NACRES:

NA.22

PubChem Substance ID:

57646910

eCl@ss:

39031308

UNSPSC Code:

12352100

EC Number:

203-150-7

MDL number:

MFCD00008674

Beilstein/REAXYS Number:

606468

Assay:

99%

Form:

solid

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Properties

vapor density

4.65 (vs air)

Quality Level

200

vapor pressure

1 mmHg ( 114 °C)

assay

99%

form

solid

autoignition temp.

1004 °F

bp

304 °C (lit.)

mp

113-115 °C (lit.)

functional group

amide

SMILES string

CC(=O)Nc1ccccc1

InChI

1S/C8H9NO/c1-7(10)9-8-5-3-2-4-6-8/h2-6H,1H3,(H,9,10)

InChI key

FZERHIULMFGESH-UHFFFAOYSA-N

Description

General description

Acetanilide undergoes palladium-catalyzed cross-coupling reaction to form ortho-acylacetanilide.

Application

Acetanilide is used as a EOF (electroosmotic flow) marker in the studies of affinity capillary electrophoresis for drug–protein binding.

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pictograms

GHS07

signalword

Warning

hcodes

H302

pcodes

P264 - P270 - P301 + P312 - P501

Hazard Classifications

Acute Tox. 4 Oral

Storage Class

11 - Combustible Solids

wgk

WGK 1

flash_point_f

321.8 °F - closed cup

flash_point_c

161 °C - closed cup

ppe

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

危险化学品

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Toluene derivatives as simple coupling precursors for cascade palladium-catalyzed oxidative C-H bond acylation of acetanilides.

Yinuo Wu et al.

Chemical communications (Cambridge, England), 49(7), 689-691 (2012-12-12)

A palladium-catalyzed cascade cross-coupling of acetanilide and toluene for the synthesis of ortho-acylacetanilide is described. Toluene derivatives can act as effective acyl precursors (upon sp(3)-C-H bond oxidation by a Pd/TBHP system) in the oxidative coupling between two C-H bonds. This

Application of a LC-MS/MS method developed for the determination of p-phenylenediamine, N-acetyl-p-phenylenediamine and N,N-diacetyl-p-phenylenediamine in human urine specimens.

Khaled M Mohamed et al.

Biomedical chromatography : BMC, 30(12), 1922-1927 (2016-05-25)

Cases of poisoning by p-phenylenediamine (PPD) are detected sporadically. Recently an article on the development and validation of an LC-MS/MS method for the detection of PPD and its metabolites, N-acetyl-p-phenylenediamine (MAPPD) and N,N-diacetyl-p-phenylenediamine (DAPPD) in blood was published. In the

Enhanced removal of Orange G from aqueous solutions by modified chitosan beads: Performance and mechanism.

Zetty Azalea Sutirman et al.

International journal of biological macromolecules, 133, 1260-1267 (2019-05-03)

Grafting of crosslinked chitosan with monomer, N-vinyl-2-pyrrolidone, has been carried out to investigate its adsorption capacity toward Orange G (OG) from aqueous solutions. The adsorption performance of modified chitosan (cts(x)-g-PNVP) was examined and compared with that of the unmodified chitosan.

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Global Trade Item Number

SKU	GTIN
112933-100G	04061838700544
112933-1KG	04061838700551
112933-500G	04061838700568
112933-5G	04061838700575