143650
5H-Dibenz[b,f]azepine
97%
Synonym(s):
Iminostilbene
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About This Item
Empirical Formula (Hill Notation):
C14H11N
CAS Number:
Molecular Weight:
193.24
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
205-970-0
Beilstein/REAXYS Number:
1343358
MDL number:
Assay:
97%
Quality Level
assay
97%
mp
196-199 °C (lit.)
solubility
ethyl acetate: soluble 25 mg/mL, clear, yellow to orange
SMILES string
N1c2ccccc2C=Cc3ccccc13
InChI
1S/C14H11N/c1-3-7-13-11(5-1)9-10-12-6-2-4-8-14(12)15-13/h1-10,15H
InChI key
LCGTWRLJTMHIQZ-UHFFFAOYSA-N
General description
5H-Dibenz[b,f]azepine, a tricyclic amine with a seven-membered ring, is commonly known as iminostilbene. It is used as an intermediate or a starting material in the synthesis of many anticonvulsant drugs.
Application
5H-Dibenz[b,f]azepine can be used:
- As a starting material to prepare pharmacologically important dibenzoazepine-pyridazine derivatives.
- To synthesize 3-chloro-1-(5H-dibenz[b,f]azepine-5yl)propan-1-one, a key intermediate used to prepare aminophenol derivatives.
- In the synthesis of dibenzazepine derivatives.
- As a starting material to synthesize olefinic multidentate ligand, which is used to prepare Rh(I) complexes.
Biochem/physiol Actions
2-(Bromomethyl)naphthalene is a fluorescent alkyl bromide. It causes the esterification of free carboxyl groups formed at the surface of polyethylene terephthalate by enzyme hydrolysis. It acts as organic electrophile in the P4S10/acyloin reaction.
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Chronic 2
Storage Class
11 - Combustible Solids
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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Synthesis and Calorimetry of Some Derivatives of Dibenzazepine
Analytical Calorimetry (1970)
Synthesis and Calorimetry of Some Derivatives of Dibenzazepine.
Gipstein E, et al.
Analytical Calorimetry, 127-134 (1970)
A Varenne et al.
Journal of immunological methods, 186(2), 195-204 (1995-10-26)
As part of our ongoing work to extend the range of applications of the non-isotopic carbonyl metalloimmunoassay (CMIA), previously developed in our laboratory, we describe here the first CMIA study of carbamazepine. The CMIA method uses a metal carbonyl complex
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 143650-5G | 04061833020746 |
| 143650-1G | 04061826238455 |