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160512

Fmoc chloride

Name: Fmoc chloride
Brand: ALDRICH

97%, for peptide synthesis

Synonym(s):

9-Fluorenylmethoxycarbonyl chloride, 9-Fluorenylmethyl chloroformate, Fmoc-Cl

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About This Item

Empirical Formula (Hill Notation):

C₁₅H₁₁ClO₂

CAS Number:

28920-43-6

Molecular Weight:

258.70

NACRES:

NA.22

PubChem Substance ID:

24849875

UNSPSC Code:

12352108

EC Number:

249-313-6

MDL number:

MFCD00001138

Beilstein/REAXYS Number:

2279177

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Properties

Product Name

Fmoc chloride, 97%

Quality Level

200

assay

97%

form

solid

mp

62-64 °C (lit.)

application(s)

peptide synthesis

functional group

Fmoc, chloro

storage temp.

2-8°C

SMILES string

ClC(=O)OCC1c2ccccc2-c3ccccc13

InChI

1S/C15H11ClO2/c16-15(17)18-9-14-12-7-3-1-5-10(12)11-6-2-4-8-13(11)14/h1-8,14H,9H2

InChI key

IRXSLJNXXZKURP-UHFFFAOYSA-N

Description

Application

Amino acid derivatizing agent for HPLC analysis. N-protecting reagent for peptide and oligonucleotide syntheses.

Reagent for amino group protection recently used in the synthesis of a bicyclic proline analog.

Reagent for derivatizing amino acids for HPLC amino acid analysis and for preparing N-Fmoc amino acids for solid-phase peptide synthesis.

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pictograms

GHS05

signalword

Danger

hcodes

H314

pcodes

P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

supp_hazards

EUH029

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Journal of the Chemical Society. Chemical Communications, 369-369 (1993)

Matrix effects in the derivatization of amino acids with naphthalene dicarboxaldehyde, 9-fluorenylmethyl chloroformate and phenylisothiocyanate.

F Lai et al.

BioTechniques, 14(4), 642-649 (1993-04-01)

Pre-column derivatizations of amino acids often present two major challenges: 1) automation, due to the multi-step manipulations for pH control, reagent addition, mixing and extraction, and 2) effect of matrices in the sample such as salts, buffers and surfactants. Both

Synthesis, 3122-3122 (2006)

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Global Trade Item Number

SKU	GTIN
160512-1G	04061838745620
160512-25G	04061835521166
160512-5G	04061835515356