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Merck
CN

176427

Silver p-toluenesulfonate

≥99%

Synonym(s):

p-Toluenesulfonic acid silver salt, Silver tosylate

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About This Item

Linear Formula:
CH3C6H4SO3Ag
CAS Number:
Molecular Weight:
279.06
UNSPSC Code:
12352302
NACRES:
NA.23
PubChem Substance ID:
EC Number:
240-859-0
Beilstein/REAXYS Number:
3598937
MDL number:
Assay:
≥99%
Form:
powder
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Quality Level

assay

≥99%

form

powder

reaction suitability

core: silver, reagent type: catalyst

application(s)

PEM fuel cells
material synthesis precursor

SMILES string

[Ag+].Cc1ccc(cc1)S([O-])(=O)=O

InChI

1S/C7H8O3S.Ag/c1-6-2-4-7(5-3-6)11(8,9)10;/h2-5H,1H3,(H,8,9,10);/q;+1/p-1

InChI key

JUDUFOKGIZUSFP-UHFFFAOYSA-M

Application

Converts alkyl halides to tosylates, and benzyl selenyl chlorides into their corresponding selenyl tosylates.


pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves



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Articles

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The Journal of Organic Chemistry, 56, 2781-2781 (1991)
Mohamed Ashraf Ali et al.
Journal of enzyme inhibition and medicinal chemistry, 26(1), 149-153 (2010-06-30)
A series of bis dihydropyrimidine compounds were synthesised by reacting dapsone with acetylacetoacetate to produce N1-4-[4-(2-oxopropylcarboxamido) phenylsulphonyl] phenyl-3-oxobutanamide, then treated with guanidine hydrochloride and an appropriate aldehyde with a catalytic amount of p-toluene sulphonic acid (PTSA) in the presence of
Aditya Kulkarni et al.
Organic letters, 13(19), 5124-5127 (2011-09-10)
An environmentally benign procedure for the hydrogenation of unprotected indoles is described. The hydrogenation reaction is catalyzed by Pt/C and activated by p-toluenesulfonic acid in water as a solvent. The efficacy of the method is illustrated by the hydrogenation of



Global Trade Item Number

SKUGTIN
176427-10G04061838752895
176427-25G04061833595121