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193453

1,3-Dimethyl-2-imidazolidinone

reagent grade

Synonym(s):

N,N′-Dimethylethyleneurea, DMEU, DMI

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About This Item

Empirical Formula (Hill Notation):
C5H10N2O
CAS Number:
80-73-9
Molecular Weight:
114.15
NACRES:
NA.22
PubChem Substance ID:
24851595
UNSPSC Code:
12352005
EC Number:
201-304-8
MDL number:
MFCD00003188
Beilstein/REAXYS Number:
108808
Assay:
97.5 % (GC)
Form:
liquid
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grade

reagent grade

Quality Level

200

assay

97.5 % (GC)

form

liquid

refractive index

n20/D 1.472 (lit.)

bp

224-226  °C, 224-226 °C (lit.)

mp

46.8  °F

solubility

toluene: soluble(lit.), water: miscible

density

1.056  g/mL at 25 °C, 1.056 g/mL at 25 °C (lit.)

SMILES string

CN1CCN(C)C1=O

InChI

1S/C5H10N2O/c1-6-3-4-7(2)5(6)8/h3-4H2,1-2H3

InChI key

CYSGHNMQYZDMIA-UHFFFAOYSA-N

General description

1,3-Dimethyl-2-imidazolidinone constitutes the mobile phase during size-exclusion chromatographic analysis of cellulose.

Application

1,3-Dimethyl-2-imidazolidinone was used as substitute solvent for toxic HMPA in the synthesis of 1,2-bis(trimethylsilyl)benzene. It was employed as solvent during α-regioselective prenylation of imines.

Other Notes

Solvent used in various synthetic organic transformations. Studied in the formation of functionally stabilized hydrosilanediyl-transition metal complexes produced photochemically from arylsilanes.

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signalword

Danger

wgk

WGK 2

flash_point_f

219.2 °F - closed cup

flash_point_c

104 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Repr. 1B

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

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Certificates of Analysis (COA)

Lot/Batch Number
STBL1141
STBK9234
STBK7812
STBK5487
STBK3139

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Tsugio Kitamura et al.
The Journal of organic chemistry, 78(7), 3421-3424 (2013-03-20)
A practical and safe synthesis of 1,2-bis(trimethylsilyl)benzene from 1,2-dichlorobenzene and Me3SiCl was achieved by use of a hybrid metal of Mg and CuCl in the presence of LiCl in 1,3-dimethyl-2-imidazolidinone (DMI). This method does not require a toxic HMPA, provides
Li-Ming Zhao et al.
Organic letters, 14(3), 886-889 (2012-01-24)
A highly α-regioselective prenylation of imines has been successfully developed. The efficiency of this approach is confirmed by a wide range of imines including N- and C-aryl aldimines, N-alkyl aldimines, C-alkyl aldimines, and N- and C-aryl ketimines. The approach uses
K Krüger et al.
Scandinavian journal of medicine & science in sports, 25(3), e283-e291 (2014-09-30)
Different types of exercise are characterized by the ability to induce specific physiological stimuli that might be able to induce the mobilization of progenitor cells. The aim of the current study was to investigate the mobilization of hematopoietic progenitor cells
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Global Trade Item Number

SKUGTIN
193453-1KG04061838760784
193453-100G04061838118462
193453-25G04061838760791