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Merck
CN

201138

Ammonium hexafluorophosphate

≥95%

Synonym(s):

Ammonium hexafluophosphate, Ammonium hexafluorophosphate V, Ammonium phosphorus hexafluoride, Ammoniumhexafluorophosphate

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About This Item

Linear Formula:
NH4PF6
CAS Number:
Molecular Weight:
163.00
PubChem Substance ID:
eCl@ss:
38070413
UNSPSC Code:
12352302
NACRES:
NA.22
EC Number:
241-009-1
MDL number:
Assay:
≥95%
Concentration:
≤100%
Form:
solid
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Quality Level

assay

≥95%

form

solid

concentration

≤100%

solubility

water: soluble ca.50 g/L

density

2.18 g/mL at 25 °C (lit.)

SMILES string

[H][N+]([H])([H])[H].F[P-](F)(F)(F)(F)F

InChI

1S/F6P.H3N/c1-7(2,3,4,5)6;/h;1H3/q-1;/p+1

InChI key

NIZXKAYXSNUDOU-UHFFFAOYSA-O

Application

Ammonium hexafluorophosphate (NH4PF6) can be used as a precursor for the preparation of:
  • Metal complexes, particularly iridium and rhodium complexes.       
  • Flame retardant cellulose-based materials.       
  • Cyclic amidinium and iminium ammonium hexafluorophosphate salts.        
  • The polymer-supported iridium isomerization catalyst for the selective trans isomerization of aryl allylic derivatives.



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wgk

WGK 3

pictograms

Corrosion

signalword

Danger

hcodes

Hazard Classifications

Skin Corr. 1B

Storage Class

8B - Non-combustible corrosive hazardous materials

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges



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Ammonium Hexafluorophosphate as a Flame Retardant for Cellulose.
Mohamed, K Syed and Padma, DK
Journal of fire sciences, 5(1), 17-24 (1987)
Accelerated luminophore discovery through combinatorial synthesis.
Lowry, Michael S et al.
Journal of the American Chemical Society, 126(43), 14129-14135 (2004)
Preparation, crystal structures and spectroscopic properties of chloro (pentane-2, 4-dionato){1, 1, 1-tris (dimethylphosphinomethyl) ethane}chromium (III), cobalt (III) and rhodium (III) hexafluorophosphate: comparison of the M-P, M-Cl and M-O (M= Cr, Co a
Suzuki T, et al.
Polyhedron, 21(8), 835-841 (2002)



Global Trade Item Number

SKUGTIN
201138-100G04061838764188
201138-25G04061838252333
201138-500G04061838118523