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Merck
CN

202991

Cerium(III) nitrate hexahydrate

99.999% trace metals basis

Synonym(s):

Cerium trinitrate, Cerous nitrate hexahydrate, Nitric acid cerium salt

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About This Item

Linear Formula:
Ce(NO3)3 · 6H2O
CAS Number:
Molecular Weight:
434.22
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
233-297-2
MDL number:
Assay:
99.999% trace metals basis
Form:
crystals and lumps
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Quality Level

assay

99.999% trace metals basis

form

crystals and lumps

reaction suitability

core: cerium, reagent type: catalyst

impurities

≤15.0 ppm Trace Metal Analysis

SMILES string

[Ce+3].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/Ce.3NO3.6H2O/c;3*2-1(3)4;;;;;;/h;;;;6*1H2/q+3;3*-1;;;;;;

InChI key

QQZMWMKOWKGPQY-UHFFFAOYSA-N

General description

Cerium (III) nitrate hexahydrate is a widely used source of cerium in materials science. It is a white-to-yellow crystalline salt that is hygroscopic and air-sensitive. It is highly soluble in water, alcohol, and acetone, although solutions can appear slightly hazy. Like many trivalent metal nitrates, cerium (III) nitrate hexahydrate melts at a low temperature (57 °C)and thermally decomposes at low temperatures too, beginning at 190 °C and proceeding rapidly at 280 °C with complete decomposition to cerium oxide at 390-400 °C.

Application

Cerium (III) nitrate hexahydrate is widely used as a source of cerium, especially in the synthesis of micro- or nano-structured ceria (cerium oxide). Because of its high solubility and low decomposition temperature, cerium (III) nitrate hexahydrate is an ideal reagent for hydrothermal reactions, sol-gel processing, and co-precipitation and calcination reactions. Our cerium (III) nitrate hexahydrate 99.999% is designed for applications that demand high-purity cerium with low contaminants of other trace metals and rare earth metals. For example, high-purity cerium nitrate is applicable in studies using cerium (III) nitrate hexahydrate used to dope catalysts, such as recent efforts to boost water splitting using Ce-doped layered double hydroxides . It is also applicable in studies using cerium (III)nitrate hexahydrate to build a ceria support for single-atom catalysts, such as nickel-doped ceria for the hydrogenation of acetylene and platinum-doped ceria for carbon monoxide oxidation. Our high-purity cerium (III) nitrate hexahydrate is also in the solid-state synthesis of cerium-doped phosphors like Ca2YHf2Al3O12 where energy transfer from Ce3+ to other rare earth ions plays a major role in the efficiency and breadth of excitations.


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pictograms

CorrosionEnvironment

signalword

Danger

hcodes

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1

Storage Class

5.1B - Oxidizing hazardous materials

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

Regulatory Information

危险化学品

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Articles

Lanthanide ions in spectral conversion enhance solar cell efficiency via photon conversion.

Rare earth elements are vital in everyday life worldwide: catalysts in cars, colors in screens, magnets in electronics. Essential for modern living.


Huajie Xu et al.
ACS applied materials & interfaces, 10(7), 6336-6345 (2018-02-01)
Developing convenient doping to build highly active oxygen evolution reaction (OER) electrocatalysts is a practical process for solving the energy crisis. Herein, a facile and low-cost in situ self-assembly strategy for preparing a Ce-doped NiFe-LDH nanosheets/nanocarbon (denoted as NiFeCe-LDH/CNT, LDH
Eleonora Venezia et al.
Nanomaterials (Basel, Switzerland), 9(4) (2019-04-27)
An important segment of the future renewable energy economy is the implementation of novel energy generation systems. Such electrochemical systems are solid oxide fuel cells, which have the advantage of direct conversion of the chemical energy stored in the fuel
Pratik P Dholabhai et al.
Physical chemistry chemical physics : PCCP, 17(23), 15375-15385 (2015-05-23)
Grain boundaries (GBs) dictate vital properties of nanocrystalline doped ceria. Thus, to understand and predict its properties, knowledge of the interaction between dopant-defect complexes and GBs is crucial. Here, we report atomistic simulations, corroborated with first principles calculations, elucidating the



Global Trade Item Number

SKUGTIN
202991-125G04061838765475
202991-25G04061838765482