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Merck
CN

208272

Vanadium(III) chloride

97%

Synonym(s):

Vanadium trichloride

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About This Item

Linear Formula:
VCl3
CAS Number:
Molecular Weight:
157.30
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
231-744-6
MDL number:
Assay:
97%
Form:
powder
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Quality Level

assay

97%

form

powder

reaction suitability

core: vanadium, reagent type: catalyst

density

3 g/mL at 25 °C (lit.)

SMILES string

Cl[V](Cl)Cl

InChI

1S/3ClH.V/h3*1H;/q;;;+3/p-3

InChI key

HQYCOEXWFMFWLR-UHFFFAOYSA-K

General description

Vanadium(III) chloride is a crystalline solid with variable oxidation states. It is widely used as a catalyst in organic synthesis, polymerization processes, and redox batteries. It acts as a reducing agent.

Application

Vanadium chloride may be used as a reduction agent to determine nitrates and nitrites in water samples.It may be used in redox flow batteries. Vanadium trichloride catalyses Pinacol coupling reactions of benzaldehyde in water. it also acts as a mild and efficient catalyst for the chemoselective deprotection of acetonides.


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pictograms

CorrosionExclamation mark

signalword

Danger

hcodes

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B

supp_hazards

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Regulatory Information

危险化学品

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Thanh-Binh Nguyen et al.
Environmental management, 63(4), 455-465 (2018-02-06)
The objective of this study was to examine the feasibility of sewage sludge composting using a simple aeration method. Two consecutive composting trials (run A and run B) using Japanese sludge and woodchips (1:1, v/v) were conducted in cubic boxes
Vanadium (III) chloride: A mild and efficient catalyst for the chemoselective deprotection of acetonides.
Sabitha G, et al.
J. Mol. Catal. A: Chem., 238(1), 229-232 (2005)
Chiara Pennesi et al.
PloS one, 8(10), e76870-e76870 (2013-11-10)
The use of dried and re-hydrated biomass of the seagrass Posidonia oceanica was investigated as an alternative and -low-cost biomaterial for removal of vanadium(III) and molybdenum(V) from wastewaters. Initial characterisation of this biomaterial identified carboxylic groups on the cuticle as



Global Trade Item Number

SKUGTIN
208272-100G04061838252456
208272-25G04061838252463
208272-5G04061838252470
208272-PZ04061823848701
208272-1G04061838769633