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Merck
CN

215120

Silicon tetrachloride

99%

Synonym(s):

STC, Tetrachlorosilane

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About This Item

Linear Formula:
SiCl4
CAS Number:
Molecular Weight:
169.90
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352103
EC Number:
233-054-0
MDL number:
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vapor density

5.86 (vs air)

Quality Level

vapor pressure

420 mmHg ( 37.7 °C)

assay

99%

form

liquid

reaction suitability

core: silicon

bp

57.6 °C (lit.)

mp

−70 °C (lit.)

density

1.483 g/mL at 25 °C (lit.)

SMILES string

Cl[Si](Cl)(Cl)Cl

InChI

1S/Cl4Si/c1-5(2,3)4

InChI key

FDNAPBUWERUEDA-UHFFFAOYSA-N

General description

Silicon tetrachloride (SiCl4) is an inorganic compound. It′s crystal structure is similar to that of carbon tetrachloride (CCl4). SiCl4 can be synthesized by the chlorination of silicon compounds (e.g. Mg2Si, SiC, SiO2/C).

Application

SiCl4 may be used;
  • in the preparation of high purity silicon, high purity silicon derived from silicon tetrachloride may find major applications in the semiconductors industry and in photovoltaic cells.
  • to dealuminate zeolite, mordenite.
  • as a coupling agent for the synthesis of amine from carboxylic acid and an amide.
  • in the synthesis of nanosilica.


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ppe

Faceshields, Gloves, Goggles

pictograms

Skull and crossbonesCorrosion

signalword

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Dam. 1 - Skin Corr. 1A - STOT SE 3

target_organs

Respiratory system

supp_hazards

Storage Class

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

危险化学品

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Articles

atomic layer deposition (ALD), microelectronics, Mo:Al2O3 films, nanocomposite coating, photovoltaics, semiconductor devices, W:Al2O3 films, composite films, layer-by-layer

Spintronics offer breakthroughs over conventional memory/logic devices with lower power, leakage, saturation, and complexity.

The properties of many devices are limited by the intrinsic properties of the materials that compose them.

View All Articles

Zeolites treated with silicon tetrachloride vapour. IV. Acidity.
Anderson MW and Klinowski J
Zeolites, 6(6), 455-466 (1986)
Silicon tetrachloride as a coupling reagent for amide formation
Chan TH and Wong LTL
The Journal of Organic Chemistry, 34(9), 2766-2767 (1969)
Verma NK , et al.
Comprehensive Chemistry XI null



Global Trade Item Number

SKUGTIN
215120-100G04061838773425
215120-1KG04061838773432