235083
Sodium bis(trimethylsilyl)amide
95%
Synonym(s):
Hexamethyldisilazane sodium salt
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About This Item
Linear Formula:
[(CH3)3Si]2NNa
CAS Number:
Molecular Weight:
183.37
UNSPSC Code:
12352111
NACRES:
NA.22
PubChem Substance ID:
EC Number:
213-983-8
Beilstein/REAXYS Number:
3629917
MDL number:
Assay:
95%
Form:
powder or chunks
Quality Level
assay
95%
form
powder or chunks
bp
202 °C/at 1-3 hPa
mp
171-175 °C (lit.), 175-171 °C (lit.)
SMILES string
C[Si](C)(C)N([Na])[Si](C)(C)C
InChI
1S/C6H18NSi2.Na/c1-8(2,3)7-9(4,5)6;/h1-6H3;/q-1;+1
InChI key
WRIKHQLVHPKCJU-UHFFFAOYSA-N
Application
Useful for the generation of carbenes, the amination of sulfenamides, and the preparation of lanthanide complexes.
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
supp_hazards
Storage Class
8A - Combustible corrosive hazardous materials
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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Articles
Discover AdQPhos and its Pd pre-catalysts for selective α-arylation of diverse nucleophiles under mild aqueous conditions without hazardous solvents.
Journal of the Chemical Society. Perkin Transactions 1, 1923-1923 (1992)
Journal of the American Chemical Society, 116, 7637-7637 (1994)
Angewandte Chemie (International Edition in English), 32, 1208-1208 (1993)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 235083-100G | 04061838784926 |
| 235083-25G | 04061838784933 |
| 235083-5G | 04061838784940 |