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Merck
CN

241059

Tetraethylammonium bromide

99%, crystals, suitable for for general lab use, ReagentPlus®

Synonym(s):

TEAB, TEA bromide

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About This Item

Linear Formula:
(C2H5)4N(Br)
CAS Number:
Molecular Weight:
210.16
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352107
EC Number:
200-769-4
MDL number:
Beilstein/REAXYS Number:
3563430
Assay:
99%
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Product Name

Tetraethylammonium bromide, ReagentPlus®, 99%

Quality Level

product line

ReagentPlus®

assay

99%

form

crystals

reaction suitability

core: ammonium

dilution

(for general lab use)

impurities

1% triethylamine hydrobromide

pH

6.5 (100 g/L)

mp

285 °C (dec.) (lit.)

SMILES string

[Br-].CC[N+](CC)(CC)CC

InChI

1S/C8H20N.BrH/c1-5-9(6-2,7-3)8-4;/h5-8H2,1-4H3;1H/q+1;/p-1

InChI key

HWCKGOZZJDHMNC-UHFFFAOYSA-M

Application

  • Tetraethylammonium bromide (TEAB) catalyzes the synthesis of thioesters by the oxidative coupling of aldehydes or alcohols with thiols or disulfides.
  • It is used as a catalyst, along with o-iodoxybenzoic acid (IBX), in the oxidation of sulfides to sulfoxides and primary carboxamides to one-carbon dehomologated nitriles.
  • TEAB can also be used as an organic template to synthesize zeolite beta.

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany


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hcodes

Hazard Classifications

Aquatic Chronic 3

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

361.4 °F - closed cup

flash_point_c

183 °C - closed cup

ppe

dust mask type N95 (US), Eyeshields, Gloves



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Tetraethylammonium Bromide-Catalyzed Oxidative Thioesterification of Aldehydes and Alcohols.
Zhu, Xuebin et al.
advanced synthesis and catalysis, 355(18), 3558-3562 (2013)
Masoumeh Taherimehr et al.
ChemSusChem, 10(6), 1283-1291 (2016-12-20)
Metal-organic frameworks (MOFs) with accessible Lewis acid sites are finding increasing application in the field of heterogeneous catalysis. However, the structural instability of MOFs when they are exposed to high temperature and/or high pressure often limits their applicability. In this
Hydrothermal crystallization of zeolite beta using tetraethylammonium bromide.
Eapen M
Zeolites, 14(4), 295-302 (1994)



Global Trade Item Number

SKUGTIN
241059-250G04061824485967
241059-50G04061824485974