248592
Bismuth(III) nitrate pentahydrate
98%, reagent grade, crystals
Synonym(s):
Bismuth trinitrate pentahydrate
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About This Item
Linear Formula:
Bi(NO3)3 · 5H2O
CAS Number:
Molecular Weight:
485.07
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
EC Number:
233-791-8
Product Name
Bismuth(III) nitrate pentahydrate, reagent grade, 98%
grade
reagent grade
Quality Level
assay
98%
form
crystals
reaction suitability
core: bismuth, reagent type: catalyst
bp
75-80 °C (lit.)
mp
30 °C (lit.)
SMILES string
O=[N+](O[Bi](O[N+]([O-])=O)O[N+]([O-])=O)[O-].C
InChI
1S/CH4.Bi.3NO3/c;;3*2-1(3)4/h1H4;;;;/q;+3;3*-1
InChI key
DPLOIMSBRDLLRI-UHFFFAOYSA-N
General description
Bismuth(III) nitrate pentahydrate is the hydrated form of bismuth(III) nitrate. It is effectively used as a Lewis acid catalyst in organic synthesis for the conversion of thiocarbonyls to their carbonyl compounds; aromatic nitration; protection of carbonyl compounds; Michael reactions, and synthesis of coumarins.
Application
An excellent oxidant for a variety of 4-substituted Hantzsch 1,4-dihydropyridines. Convenient reagent for selective oxidation of sufides to sulfoxides.
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signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Ox. Sol. 2
Storage Class
5.1B - Oxidizing hazardous materials
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
Regulatory Information
危险化学品
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Mashraqui, S.H. Karnik, M.A.
Synthesis, 713-713 (1998)
Mashraqui, S.H. et al.
Synthetic Communications, 28, 939-939 (1998)
Na Li et al.
Dalton transactions (Cambridge, England : 2003), 43(36), 13742-13750 (2014-08-12)
The xFe2O3/yBiOCl composites (xFe/yBi, x/y = 0/100, 5/100, 10/100, 20/100, 30/100 and 40/100 molar ratios) are prepared for the first time through an in situ hydrolysis method under hydrothermal conditions. The samples are characterized by X-ray diffraction (XRD), scanning electron
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 248592-500G | 04061838252708 |
| 248592-100G | 04061825928234 |