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Merck
CN

267112

Palladium

wire, diam. 1.0 mm, 99.9% trace metals basis

Synonym(s):

Palladium (powder), Palladium black, Palladium element

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About This Item

Linear Formula:
Pd
CAS Number:
Molecular Weight:
106.42
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12141733
EC Number:
231-115-6
MDL number:
eCl@ss:
38191001
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Quality Level

assay

99.9% trace metals basis

form

wire

reaction suitability

core: palladium

resistivity

9.96 μΩ-cm, 20°C

diam.

1.0 mm

bp

2970 °C (lit.)

mp

1554 °C (lit.)

density

12.02 g/cm3 (lit.)

SMILES string

[Pd]

InChI

1S/Pd

InChI key

KDLHZDBZIXYQEI-UHFFFAOYSA-N

Application

Palladium is widely used as a metal wire electrode to synthesize Pd-based nanomaterials with good electrocatalytic activity. For example, it is used to prepare carbon-supported Pd nanoclusters and PdAu nanoparticles.

Itcan also be used as a hydrogenation catalyst in various organic reactions, suchas hydrogenation of alkenes and alkynes to their corresponding hydrocarbons.

Preparation Note

900 mg = 10 cm; 9 g = 100 cm


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Storage Class

13 - Non Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

Regulatory Information

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Meifang Zheng et al.
Organic letters, 15(8), 1838-1841 (2013-04-02)
Palladium-catalyzed oxidative difunctionalization of enol ethers with 1,3-dicarbonyl compounds to construct trisubstituted furans in one step under mild conditions is described. The reaction is thought to proceed through a C-C bond formation along with a C-O bond closing the ring
Xuxing Chen et al.
Organic & biomolecular chemistry, 11(16), 2582-2585 (2013-03-19)
A one-pot two-step synthesis of versatile indenones has been developed. This palladium(II)-catalyzed transformation involves generation and condensation of ortho-functionalized 1,2-benzils from 2-(2-arylethynylphenyl)acetonitriles using Ph2SO as the oxidant. The resulting 3-cyanoindenones can be converted to various valuable molecules.
Xiaohu Xia et al.
Proceedings of the National Academy of Sciences of the United States of America, 110(17), 6669-6673 (2013-04-10)
Controlling the shape or morphology of metal nanocrystals is central to the realization of their many applications in catalysis, plasmonics, and electronics. In one of the approaches, the metal nanocrystals are grown from seeds of certain crystallinity through the addition



Global Trade Item Number

SKUGTIN
267112-900MG04061833606049
267112-9G04061833596159