336106
2,6-Lutidine
Synonym(s):
2,6-Dimethylpyridine
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About This Item
Empirical Formula (Hill Notation):
C7H9N
CAS Number:
Molecular Weight:
107.15
UNSPSC Code:
12352005
NACRES:
NA.22
PubChem Substance ID:
EC Number:
203-587-3
Beilstein/REAXYS Number:
105690
MDL number:
Assay:
≥99.0 %
Form:
liquid
assay
≥99.0 %
Quality Level
form
liquid
refractive index
n20/D 1.497 (lit.)
bp
143-145 °C (lit.)
mp
−6 °C (lit.)
solubility
water: 163.130 g/L at 25 °C
density
0.92 g/mL at 25 °C (lit.)
SMILES string
Cc1cccc(C)n1
InChI
1S/C7H9N/c1-6-4-3-5-7(2)8-6/h3-5H,1-2H3
InChI key
OISVCGZHLKNMSJ-UHFFFAOYSA-N
General description
2,6-Lutidine, also known as 2,6-dimethylpyridine, is an organic compound that is commonly used as a reagent in various organic reactions, such as the synthesis of heterocycles, nitroalkenes, and alkyl halides. It can also be used as a catalyst in organic synthesis.
Application
2,6-Lutidine can be used as:
- A base in the synthesis of an aldol adduct from malonic acid hemithioesters and aldehydes catalyzed by Cu(II) salt.
- An additive in reductive cyclization of epoxygeranyl acetate.
- A catalyst in combination with CuI for selective synthesis of N-sulfonyl-1,2,3-triazoles.
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signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2
Storage Class
3 - Flammable liquids
wgk
WGK 3
flash_point_f
89.6 °F
flash_point_c
32 °C
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Regulatory Information
危险化学品
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Cu (II)-catalyzed enantioselective aldol condensation between malonic acid hemithioesters and aldehydes.
Orlandi S, et al.
Tetrahedron Letters, 45(8), 1747-1749 (2004)
Ti (III)-catalyzed radical cyclization of 6, 7-epoxygeranyl acetate.
Fuse S, et al.
Tetrahedron Letters, 45(9), 1961-1963 (2004)
Copper-Catalyzed Synthesis of N-Sulfonyl-1, 2, 3-triazoles: Controlling Selectivity.
Yoo EJ, et al.
Angewandte Chemie (International Edition in English), 46(10), 1730-1733 (2007)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 336106-100ML | 04061826742815 |
| 336106-190UL | 04061837672514 |
| 336106-1L | 04061837672521 |
| 336106-2L | 04061826742822 |
| 336106-5L | 04022536025919 |
| 336106-PZ | 04061826597422 |