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357790

Thianaphthene

Name: Thianaphthene
Brand: ALDRICH

98%

Synonym(s):

Benzo[b]thiophene, Benzothiophene, Thionaphthene

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About This Item

Empirical Formula (Hill Notation):

C₈H₆S

CAS Number:

95-15-8

Molecular Weight:

134.20

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24861944

EC Number:

202-395-7

Beilstein/REAXYS Number:

80580

MDL number:

MFCD00005864

Assay:

98%

Form:

solid

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Properties

Quality Level

100

assay

98%

form

solid

bp

221-222 °C (lit.)

mp

30-33 °C (lit.)

density

1.149 g/mL at 25 °C (lit.)

SMILES string

c1ccc2sccc2c1

InChI

1S/C8H6S/c1-2-4-8-7(3-1)5-6-9-8/h1-6H

InChI key

FCEHBMOGCRZNNI-UHFFFAOYSA-N

Description

General description

Reaction of ethyl diazoacetate with thianaphthene has been reported.

Application

Thianaphthene may be used in the preparation of 2-thianapthenylphenyllithium, via metalation by n-butyllithium.

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pictograms

GHS07

signalword

Warning

hcodes

H302,H412

pcodes

P264 - P270 - P273 - P301 + P312 - P501

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 3

Storage Class

11 - Combustible Solids

wgk

WGK 3

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

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Reactions of ethyl diazoacetate with thianaphthene, indoles, and benzofuran.

Wenkert E, et al.

The Journal of Organic Chemistry, 42(24), 3945-3949 (1977)

Highly efficient and selective removal of N-heterocyclic aromatic contaminants from liquid fuels in a Ag(I) functionalized metal-organic framework: Contribution of multiple interaction sites.

Haiying She et al.

Journal of colloid and interface science, 518, 149-155 (2018-02-18)

An adsorbent with multiple interaction sites for the adsorption of nitrogen-containing compounds (NCCs) has been realized in a silver ion functionalized Cr3+ based metal-organic framework (Cr)-MIL-101-SO3Ag. The adsorptive denitrogenation performance of (Cr)-MIL-101-SO3Ag was evaluated in a batch adsorption system in

Some 2-Substituted Thianaphthenes Derived from 2-Thianaphthenyllithium1.

Shirley DA and Cameron MD.

Journal of the American Chemical Society, 74(3), 664-665 (1952)

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Global Trade Item Number

SKU	GTIN
357790-25G	04061831812657
357790-100G	04061831812640
357790-5G	04061831812664