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372870

Iron(II) chloride

Name: Iron(II) chloride
Brand: ALDRICH

98%, powder

Synonym(s):

Ferrous chloride, Iron dichloride

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About This Item

Linear Formula:

FeCl₂

CAS Number:

7758-94-3

Molecular Weight:

126.75

NACRES:

NA.22

PubChem Substance ID:

24863176

UNSPSC Code:

12161600

EC Number:

231-843-4

MDL number:

MFCD00011004

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Properties

Product Name

Iron(II) chloride, 98%

Quality Level

100

assay

98%

form

powder

reaction suitability

core: iron, reagent type: catalyst
reaction type: Atom Transfer Radical Polymerization (ATRP)

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

677 °C (lit.)

density

3.16 g/mL at 25 °C (lit.)

greener alternative category

, Aligned

SMILES string

Cl[Fe]Cl

InChI

1S/2ClH.Fe/h2*1H;/q;;+2/p-2

InChI key

NMCUIPGRVMDVDB-UHFFFAOYSA-L

Description

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. The iron catalysts are known to be inexpensive and environmentally benign. Click here for more information.

Application

Iron(II) chloride can be used to catalyze:

The preparation of Grignard compounds, such as 1-naphthylmagnesium chloride.
The selective oxidation of 2,4,6-trimethylphenol (2,4,6-TMP) to 3,5-dimethyl-4-hydroxybenzaldehyde (DMHB) in the presence of acetoxime.
Raney-type catalysts modified with FeCl₂ show enhanced selective hydrogenation of an α,β-unsaturated aldehyde to an unsaturated alcohol.

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pictograms

GHS05,GHS07

signalword

Danger

hcodes

H302,H318

pcodes

P264 - P270 - P280 - P301 + P312 - P305 + P351 + P338 - P501

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1

Storage Class

8B - Non-combustible corrosive hazardous materials

wgk

WGK 1

flash_point_f

does not flash

flash_point_c

does not flash

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

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Protocols

Concepts and Tools for RAFT Polymerization

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

Typical Procedures for Polymerizing via RAFT

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

Polymerizing via ATRP

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

Articles

Micro Review of RAFT Polymerization

Micro review of reversible addition/fragmentation chain transfer (RAFT) polymerization.

Liquid-phase Selective Hydrogenation of an Aliphatic ?, ?-Unsaturated Aldehyde over Raney Cobalt Catalyst Modified with Ferrous Chloride.

Hotta K, et al.

Bulletin of the Chemical Society of Japan, 42(5), 1447-1449 (1969)

2, 4, 6-Trimethylphenol oxidation with ferrous chloride catalyst: Effect of acetoxime addition.

Li K, et al.

J. Mol. Catal. A: Chem., 241(1-2), 72-78 (2005)

Transition metal catalyzed preparation of Grignard compounds.

Bogdanovic B, et al.

Angewandte Chemie (International Edition in English), 39(24), 4610-4612 (2000)

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Global Trade Item Number

SKU	GTIN
372870-250G	04061831834314
372870-25G	04061838253538