43158
(R)-(−)-2-[2-(Diphenylphosphino)phenyl]-4-phenyl-2-oxazoline
≥97.0% (31P-NMR)
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About This Item
Empirical Formula (Hill Notation):
C27H22NOP
CAS Number:
Molecular Weight:
407.44
PubChem Substance ID:
UNSPSC Code:
12352005
Beilstein/REAXYS Number:
7547072
MDL number:
assay
≥97.0% (31P-NMR)
form
solid
optical activity
[α]20/D −29.5±3°, c = 1% in chloroform
SMILES string
C1OC(=N[C@@H]1c2ccccc2)c3ccccc3P(c4ccccc4)c5ccccc5
InChI
1S/C27H22NOP/c1-4-12-21(13-5-1)25-20-29-27(28-25)24-18-10-11-19-26(24)30(22-14-6-2-7-15-22)23-16-8-3-9-17-23/h1-19,25H,20H2/t25-/m0/s1
InChI key
OKUTYUNUKKPYJS-VWLOTQADSA-N
Packaging
Bottomless glass bottle. Contents are inside inserted fused cone.
Other Notes
Chiral ligand employed in enantioselective Pd-catalyzed allylic substitution reactions
Storage Class
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Regulatory Information
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P. von Matt et al.
Angewandte Chemie (International Edition in English), 105, 614-614 (1993)
J.M.J. Williams et al.
Tetrahedron Letters, 34, 3149-3149 (1993)