438456
Sodium azide
≥99.99% trace metals basis
Synonym(s):
Hydrazoic acid sodium salt, NSC 3072
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About This Item
Linear Formula:
NaN3
CAS Number:
Molecular Weight:
65.01
UNSPSC Code:
12352302
PubChem Substance ID:
EC Number:
247-852-1
MDL number:
Assay:
≥99.99% trace metals basis
Form:
solid
Solubility:
soluble 65 g/L at 20 °C (completely)
assay
≥99.99% trace metals basis
form
solid
reaction suitability
reaction type: click chemistry
solubility
soluble 65 g/L at 20 °C (completely)
SMILES string
[Na]N=[N+]=[N-]
InChI
1S/N3.Na/c1-3-2;/q-1;+1
InChI key
PXIPVTKHYLBLMZ-UHFFFAOYSA-N
Application
Efficient 1,4-addition of azide to a,β-unsaturated aldehydes in the presence of tertiary amines.
Catalyst for:
Reagent for synthesis of
Involved in regioselective synthesis of prianosin B
Catalyst for:
- Oxidative decarboxylation
- Michael addition reactions
Reagent for synthesis of
- Blue fluorescent copolymers
- Metal phosphonates
- Arenes via aminations
Involved in regioselective synthesis of prianosin B
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signalword
Danger
Hazard Classifications
Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2 Oral
target_organs
Brain
supp_hazards
Storage Class
6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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Synthetic Communications, 37, 1027-1027 (2007)
Xiaohua Sun et al.
Organic letters, 9(22), 4495-4498 (2007-10-04)
A novel intermolecular cross-double-Michael addition between nitro and carbonyl activated olefins has been developed through Lewis base catalysis. The reaction took place with a large group of beta-alkyl nitroalkenes and alpha,beta-unsaturated ketone/esters, producing an allylic nitro compound in good to
H. Chen, et al.,
Macromolecules, 43, 3613-3623 (2010)