459925
Platinum(IV) oxide
solid
Synonym(s):
Adam’s catalyst, NSC 402624, Platinic oxide, Platinum dioxide
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About This Item
Linear Formula:
PtO2
CAS Number:
Molecular Weight:
227.08
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
215-223-0
MDL number:
Product Name
Platinum(IV) oxide,
form
solid
Quality Level
composition
Pt, 79-83%
reaction suitability
core: platinum, reagent type: catalyst
greener alternative product characteristics
Designing Safer Chemicals
Catalysis
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
surface area
≥75 m2/g
impurities
iron, low
mp
450 °C (lit.)
greener alternative category
SMILES string
O=[Pt]=O
InChI
1S/2O.Pt
InChI key
YKIOKAURTKXMSB-UHFFFAOYSA-N
General description
Prepared by Adams′ nitrate fusion method.
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Application
Catalyst for hydrogenation of various functional groups; used as dehydrogenation catalyst; used for selective oxidation of primary alcohols.
Catalyst for:
- Hydrohydrazination reactions
- Oxidation of sugars
- Low-temperature oxidation of carbon monoxide
- Oxygen reduction reaction
- Hydrogenation reactions
- Hydrogenolysis of the cyclopropyl group into an isopropyl group
- Hydroxycyclopropanation reactions
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signalword
Danger
hcodes
Hazard Classifications
Ox. Sol. 1
Storage Class
5.1A - Strongly oxidizing hazardous materials
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
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Development of GSKDevelopment of GSK's reagent guides ? embedding sustainability into reagent selections reagent guides ? embedding sustainability into reagent selection.
Adams JP, et al.
Green Chemistry, 15, 1542-1549 (2013)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 459925-1G | 04061832343617 |
| 459925-250MG | 04061833482803 |
| 459925-5G | 04061832343624 |