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Merck
CN

463922

Ammonium metatungstate hydrate

99.99% trace metals basis

Synonym(s):

Ammonium tungsten oxide hydrate, Hexaammonium wolframate hydrate

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About This Item

Linear Formula:
(NH4)6H2W12O40 · xH2O
CAS Number:
Molecular Weight:
2956.30 (anhydrous basis)
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
234-733-4
MDL number:
Assay:
99.99% trace metals basis
Form:
powder
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Quality Level

assay

99.99% trace metals basis

form

powder

reaction suitability

reagent type: catalyst

impurities

≤150.0 ppm Trace Metal Analysis

mp

100 °C (dec.) (lit.)

SMILES string

N.N.N.N.N.N.O.O[W]1O[W](O)(=O)(O1)O[W]2(=O)(=O)O[W](O)(=O)(O2)O[W]3(=O)(=O)O[W](O)(=O)(O3)O[W]4(=O)(=O)O[W](O)(=O)(O[W]5(=O)(=O)O[W](O)(=O)(O[W]6(=O)(=O)O[W](O)(O)O6)O5)O4

InChI

1S/6H3N.9H2O.32O.12W/h6*1H3;9*1H2;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;/q;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;6*+1;+2/p-8

InChI key

ZBHPUDGBNLMJQH-UHFFFAOYSA-F

General description

Ammonium metatungstate is a Keggin-type heteropoly compound. It can be prepared by polycondensation of ammonium tungstate solutions. It is widely used as a precursor for preparing tungsten catalysts for hydrocracking and as a fuel cell catalyst.

Application

Ammonium metatungstate can be used as a precursor to synthesize:
  • Carbon-supported tungsten catalyst for hydrogenolysis of cellulose.
  • Reduced tungsten and mixed tungsten oxide catalysts for bifunctional hydroisomerization of n-alkanes.
  • Hybrid 2D/3D tungsten diselenide transistors via chemical vapor deposition method.


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pictograms

CorrosionExclamation mark

signalword

Danger

hcodes

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1

Storage Class

11 - Combustible Solids

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves



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Ze-Da Meng et al.
Nanoscale research letters, 6(1), 459-459 (2011-07-22)
WO3-treated fullerene/TiO2 composites (WO3-fullerene/TiO2) were prepared using a sol-gel method. The composite obtained was characterized by BET surface area measurements, X-ray diffraction, scanning electron microscopy, energy dispersive X-ray analysis, transmission electron microscopy, and UV-vis analysis. A methyl orange (MO) solution
Hanyu Zhang et al.
Nanoscale, 12(15), 8344-8354 (2020-04-03)
By understanding how the environmental composition impacts the optoelectronic properties of transition metal dichalcogenide monolayers, we demonstrate that simple photoluminescence (PL) measurements of tungsten disulfide (WS2) monolayers can differentiate relative humidity environments. In this paper, we examine the PL and
Alessandro Chieregato et al.
ChemSusChem, 8(2), 398-406 (2014-12-10)
Glycerol surplus from biodiesel synthesis still represents a major problem in the biofuel production chain. Meanwhile, those in the acrylic acid market are looking for new processes that are able to offer viable alternatives to propylene-based production. Therefore, acrylic acid



Global Trade Item Number

SKUGTIN
463922-25G04061835511969